-Selective hydroxylation of alkyl aryl ethers. | LitMetric

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-Selective hydroxylation of alkyl aryl ethers. | LitMetric

-Selective hydroxylation of alkyl aryl ethers.

Runqing Zhu Qianqian Sun Jing Li Luohao Li Qinghe Gao Yakun Wang Lizhen Fang

Chem Commun (Camb)

School of Pharmacy, Xinxiang Medical University, Xinxiang, Henan 453003, People's Republic of China.

Published: December 2021

-Selective hydroxylation of alkyl aryl ethers is established, which proceeds with a ruthenium(II) catalyst, hypervalent iodine(III) and trifluoroacetic anhydride a radical mechanism. This protocol tolerates a wide scope of substrates and provides a facile and efficient method for preparing clinical drugs monobenzone and pramocaine on a gram scale.

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http://dx.doi.org/10.1039/d1cc06210g	DOI Listing

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