AI Article Synopsis

  • The study focused on multiferroic bismuth ferrite materials, specifically BiREFeO, which were doped with rare-earth elements like La, Eu, and Er using solution combustion synthesis.
  • Various techniques, including X-ray photoelectron spectroscopy and SQUID magnetometry, were used to investigate the structural, electrical, and magnetic properties of these samples.
  • The results showed that the doped ferrites exhibited strong spontaneous electrical polarization and significantly enhanced magnetization compared to other bismuth ferrites, with the BLaFO sample achieving the highest saturation magnetization at room temperature.

Article Abstract

In this work, the multiferroic bismuth ferrite materials BiREFeO doped by rare-earth (RE = La, Eu, and Er) elements were obtained by the solution combustion synthesis. Structure, electrical, and magnetic properties of prepared samples were investigated by X-ray photoelectron spectroscopy, Mössbauer spectroscopy, electrical hysteresis measurement, broadband dielectric spectroscopy, and SQUID magnetometry. All obtained nanomaterials are characterized by spontaneous electrical polarization, which confirmed their ferroelectric properties. Investigation of magnetic properties at 300.0 K and 2.0 K showed that all investigated BiREFeO ferrites possess significantly higher magnetization in comparison to bismuth ferrites obtained by different methods. The highest saturation magnetisation of 5.161 emu/g at 300.0 K was observed for the BLaFO sample, while at 2.0 K it was 12.07 emu/g for the BErFO sample. Several possible reasons for these phenomena were proposed and discussed.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8610975PMC
http://dx.doi.org/10.1038/s41598-021-01983-zDOI Listing

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