Previously unknown 1,10a-dihydro-1-aza-10a-boraphenanthrene and 6a,7-dihydro-7-aza-6a-boratetraphene have been efficiently synthesized. Bromination of these BN-PAHs proceeds with complete regioselectivity, resulting in the formation of different substituted derivatives via cross-coupling reactions. These compounds exhibit rather high fluorescence quantum yields (up to ϕ = 0.80).
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8650019 | PMC |
| http://dx.doi.org/10.1021/acs.joc.1c01095 | DOI Listing |
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