It is well established that mantle plumes are the main conduits for upwelling geochemically enriched material from Earth's deep interior. The fashion and extent to which lateral flow processes at shallow depths may disperse enriched mantle material far (>1,000 km) from vertical plume conduits, however, remain poorly constrained. Here, we report He and C isotope data from 65 hydrothermal fluids from the southern Central America Margin (CAM) which reveal strikingly high He/He (up to 8.9R) in low-temperature (≤50 °C) geothermal springs of central Panama that are not associated with active volcanism. Following radiogenic correction, these data imply a mantle source He/He >10.3R (and potentially up to 26R, similar to Galápagos hotspot lavas) markedly greater than the upper mantle range (8 ± 1R). Lava geochemistry (Pb isotopes, Nb/U, and Ce/Pb) and geophysical constraints show that high He/He values in central Panama are likely derived from the infiltration of a Galápagos plume-like mantle through a slab window that opened ∼8 Mya. Two potential transport mechanisms can explain the connection between the Galápagos plume and the slab window: 1) sublithospheric transport of Galápagos plume material channeled by lithosphere thinning along the Panama Fracture Zone or 2) active upwelling of Galápagos plume material blown by a "mantle wind" toward the CAM. We present a model of global mantle flow that supports the second mechanism, whereby most of the eastward transport of Galápagos plume material occurs in the shallow asthenosphere. These findings underscore the potential for lateral mantle flow to transport mantle geochemical heterogeneities thousands of kilometers away from plume conduits.
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http://dx.doi.org/10.1073/pnas.2110997118 | DOI Listing |
Microbiol Spectr
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National Center for Polar and Ocean Research, Ministry of Earth Sciences, Vasco-da-Gama, Goa, India.
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View Article and Find Full Text PDFSe Pu
January 2025
Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China.
Lipids are indispensable components of living organisms and play pivotal roles in cell-membrane fluidity, energy provision, and neurotransmitter transmission and transport. Lipids can act as potential biomarkers of diseases given their abilities to indicate cell-growth status. For example, the lipid-metabolism processes of cancer cells are distinct from those of normal cells owing to their rapid proliferation and adaptation to ever-changing biological environments.
View Article and Find Full Text PDFACS Earth Space Chem
December 2024
Department of Chemistry, University of Colorado Boulder Boulder, Colorado 80309, United States.
Iodine in the atmosphere destroys ozone and can nucleate particles by formation of iodic acid, HIO. Recent field observations suggest iodate recycles from particles sustaining significant gas-phase IO radical concentrations (0.06 pptv) in aged stratospheric air, and in elevated dust plumes.
View Article and Find Full Text PDFChemosphere
December 2024
National Institute of Aquatic Resources, Section for Oceans and Arctic, Technical University of Denmark, Henrik Dams Allé, Building 201, 2800 Kgs. Lyngby, Denmark. Electronic address:
Knowledge of contaminant distribution and transport of contaminant plumes in groundwater is important for effective remediation. Tedious and expensive laboratory analyses could be supplemented with optical measurements such as fluorescence to offer a rapid alternative with the potential for on-site measurements. Here, we explore the applicability of fluorescence spectroscopy as an on-site alternative to identifying the extent of a groundwater contaminant plume in Grindsted, Denmark.
View Article and Find Full Text PDFJ Mass Spectrom
January 2025
Department of Chemical Engineering and Chemistry, Institute for Complex Molecular Systems, Eindhoven University of Technology, Eindhoven, The Netherlands.
One critical issue in hydrogen/deuterium exchange mass spectrometry (HDX MS) analysis is the deleterious back exchange. Herein, we report that when matrix-assisted laser desorption/ionization (MALDI) is used, the MALDI process itself can also cause significant back exchange. The back exchange occurred inside the reactive MALDI plume was investigated by depositing a fully deuterated sample prepared in DO on top of a preloaded dried layer of matrix.
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