We report the synthesis and crystal structure of the first quinolino[7,8-]quinoline beryllium(II) complex of the general formula [BeL2(MeCN)Br]Br·MeCN, containing the ligand 4,9-dihydroxyquinolino[7,8-]quinoline (L2). The Be(II) cation is a great size match for the dinitrogen binding pocket of the quinolino[7,8-]quinoline ligand as indicated by minimal out-of-plane displacement and ligand distortion parameters.
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| http://dx.doi.org/10.1039/d1dt03367k | DOI Listing |
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