The electrohydrodynamics of a sessile droplet under the influence of periodic and steady electric fields in microgravity conditions is theoretically investigated using an inertial lubrication model. Previous studies have revealed that a freely suspended spherical droplet with unequal conductivity and permittivity ratios exhibits distinct dynamics under periodic and equivalent steady forcing in the root mean-square sense. However, it is unclear when (if at all) such distinct dynamics occur for periodic and equivalent steady forcing in the case of sessile droplets. The equivalence between periodic and steady forcing is shown to be governed by the interfacial charge buildup, which further depends on the competition between the charge relaxation and forcing timescales. A circulation-deformation map is introduced for the sessile droplet that acts as a guideline to achieve electric field-induced wetting or dewetting as the case may be. We also demonstrate that a droplet may be rendered either more or less wetting solely by tuning the forcing frequency.
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http://dx.doi.org/10.1038/s41526-021-00176-2 | DOI Listing |
Biomimetics (Basel)
November 2024
Faculty of Engineering, University of Nottingham, University Park, Nottingham NG7 2RD, UK.
In nature, engineering technology and daily life, wetting phenomena are widespread and have essential roles and significance. Bionics is becoming increasingly important nowadays and exploring the mechanism that influences biomimetic surface microstructure on droplet wetting process and heat and mass transfer characteristics is becoming more meaningful. In this paper, based on photolithography technology, SU-8 photoresist was used as raw material to prepare biomimetic surfaces with microstructures in various arrangements.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
East Bavarian Centre for Intelligent Materials (EBACIM), Ostbayerische Technische Hochschule Regensburg, Seybothstr. 2, Regensburg, 93053, Germany.
Hypothesis: The presence of a wetting ridge is crucial for many wetting phenomena on soft substrates. Conventional experimental observations of a wetting ridge require permanent presence of a droplet. The magnetic field-induced plasticity effect (FIPE) of soft magnetoative elastomers (MAEs) allows one to overcome this limitation.
View Article and Find Full Text PDFLangmuir
December 2024
School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore.
Extensive studies have been conducted to manipulate the morphology of sodium chloride salt crystals to tailor their physical and chemical properties. Among the myriad factors considered, the effects of the substrate and additives have profound impacts on the types of salt depositions. Surface charge effects and various ionic surfactants influence ion movement, resulting in diverse crystal morphologies.
View Article and Find Full Text PDFJ Chem Phys
November 2024
Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Pl. 1, 76344 Eggenstein-Leopoldshafen, Germany.
Variations from equilibrium Young's angle, known as contact angle hysteresis (CAH), are frequently observed upon droplet deposition on a solid surface. This ubiquitous phenomenon indicates the presence of multiple local surface energy minima for the sessile droplet. Previous research primarily explains CAH via considering macroscopic roughness, such as topographical defects, which alter the effective interfacial energy between the fluid phase and the solid phase, thereby shifting the global surface energy minimum.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
November 2024
Department of Chemistry, Purdue University, West Lafayette, IN 47907.
The extraordinary chemistry of microdroplets has reshaped how we as a community think about reactivity near multiphase boundaries. Even though interesting physico-chemical properties of microdroplets have been reported, "sessile" droplets' inherent mobility, which has been implicated as a driving force for curious chemistry, has not been well established. This paper seeks to answer the question: Can adsorbed microdroplets be mobile at the nanoscale? This is a tantalizing question, as almost no measurement technique has the spatiotemporal resolution to answer it.
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