AI Article Synopsis
- The study successfully synthesized a rhodium(I) porphyrin complex under controlled conditions.
- The presence of coordinated rhodium(I) significantly altered the molecular structure and affected the optical and electronic characteristics of the porphyrin.
- The findings suggest that porphyrin can be utilized as a new binucleating ligand to create bimetallic complexes.
Article Abstract
The first example of monovalent and bimetallic porphyrins(2.1.2.1), the rhodium(I) complex of porphyrin(2.1.2.1), was readily obtained under controlled conditions. The coordinated rhodium(I) drastically influenced the molecular structure and optical and electronic properties. Our results clearly demonstrate that porphyrin(2.1.2.1) could be developed as a new binucleating ligand for the fabrication of bimetallic complexes.
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| http://dx.doi.org/10.1039/d1cc05641g | DOI Listing |
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