A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 176

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 176
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 250
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 1034
Function: getPubMedXML

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3152
Function: GetPubMedArticleOutput_2016

File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

An Acylhydrazone-Based Fluorescent Sensor for Sequential Recognition of Al and HPO. | LitMetric

AI Article Synopsis

  • A new fluorescent sensor was created to simultaneously detect aluminum (Al) and hydrogen peroxide (HPO) through changes in fluorescence intensity.
  • The sensor can detect Al and HPO at very low concentrations, specifically 0.83 µM for Al and 1.7 µM for HPO, and operates with a 1:1 binding ratio for both substances.
  • Its effectiveness was validated through various scientific methods, including spectroscopy and test strips, showing that the sensor can repeatedly identify Al and HPO in sequence.

Article Abstract

A novel acylhydrazone-based fluorescent sensor was designed and synthesized for consecutive sensing of Al and HPO. displayed fluorometric sensing to Al and could sequentially detect HPO by fluorescence quenching. The limits of detection for Al and HPO were determined to be 0.83 and 1.7 μM, respectively. The binding ratios of to Al and -Al to HPO were found to be 1:1. The sequential recognition of Al and HPO by could be repeated consecutively. In addition, the practicality of was confirmed with the application of test strips. The sensing mechanisms of Al and HPO by were investigated through fluorescence and UV-Visible spectroscopy, Job plot, ESI-MS, H NMR titration, and DFT calculations.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8585233PMC
http://dx.doi.org/10.3390/ma14216392DOI Listing

Publication Analysis

Top Keywords

acylhydrazone-based fluorescent
8
fluorescent sensor
8
sequential recognition
8
recognition hpo
8
hpo
7
sensor sequential
4
hpo novel
4
novel acylhydrazone-based
4
sensor designed
4
designed synthesized
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!