Uranium (U(VI)) and thorium (Th(IV)) ions produced by the nuclear and mining industries cause water pollution, thereby harming the environment and human health. In this study, gadolinium oxide-decorated polyvinyl alcohol-graphene oxide composite (PGO-Gd) was developed using a simple hydrothermal process to treat U(VI) and Th(IV) ions in water. The developed material was structurally characterized by highly advanced spectroscopy and microscopy techniques. The effects of pH, equilibration time and temperature on both radionuclides (U(VI) and Th(IV)) adsorption by PGO-Gd were examined. The PGO-Gd composite adsorbed both metal ions satisfactorily, with adsorption capacities of 427.50 and 455.0 mg g at pH 4.0, respectively. The adsorption properties of both metal ions were found to be compatible with the Langmuir and pseudo-second-order kinetic models. Additionally, based on the thermodynamic characteristics, the adsorption was endothermic and spontaneous. Furthermore, the environmental viability of PGO-Gd and its application was demonstrated by studying its reusability in treating spiked surface water. PGO-Gd shows promise as an adsorbent in effectively removing both radionuclides from aqueous solutions.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587516 | PMC |
| http://dx.doi.org/10.3390/polym13213835 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A paradigm shift for evaluating natural attenuation of radioactive iodine in soils and sediments: Species-specific mechanisms and pathways.
J Environ Manage
January 2025
Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802, USA. Electronic address:
The primary approach to assessing monitored natural attenuation (MNA) is currently based on a conceptual model utilizing the total contaminant concentrations, assuming a single aqueous species. However, many contaminants, such as metals and radionuclide - including iodine, can exist in multiple species that behave chemically differently in the environment and can exist simultaneously. For example, radioiodine often occurs concurrently as three major aqueous species: iodide (I), iodate (IO), and organo-I, which undergo distinct attenuation pathways and exhibit markedly different mobility and geochemical behavior.
View Article and Find Full Text PDFFluorescence tunable carbon dots for nuclear dynamics and gastrointestinal imaging in live zebrafish and their toxicity evaluation by cardio-craniofacial disfunction assessment.
Nanoscale
January 2025
Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085, India.
Sub-cellular organelle anomalies are frequently observed in diseases such as cancer. Early and precise diagnosis of these alterations can be crucial for patient outcomes. However, current diagnostic tools using conventional organic dyes or metal quantum dots face limitations, including poor biocompatibility, stringent storage conditions, limited solubility in aqueous media, and slow staining speeds.
View Article and Find Full Text PDFFlow electrolytic separation of radionuclides for interference suppression in γ-spectrometry.
Anal Chim Acta
February 2025
Department of Chemistry and Applied Biosciences, Laboratory of Inorganic Chemistry, ETH Zürich, Vladimir-Prelog-Weg 1-5/10, Zürich, CH-8093, Switzerland; Laboratory of Radiochemistry, Centre for Nuclear Engineering and Sciences, Paul Scherrer Institute, Forschungsstrasse 111, Villigen PSI, CH-5232, Switzerland. Electronic address:
Background: The direct and accurate measurement of low-level γ-emitters in samples from nuclear facilities is a challenging task due to the presence of high activities of dominant radionuclides. In this case a complex chemical separation is required to remove interfering radionuclides prior to γ-spectrometric analysis. Several radionuclides such as, Ag, Sb, Sn and Te are of relevance for radioanalytical analysis in nuclear facilities.
View Article and Find Full Text PDFOptimized chelator and nanoparticle strategies for high-activity Pd-loaded biodegradable brachytherapy seeds.
EJNMMI Radiopharm Chem
December 2024
The Hevesy Laboratory, DTU Health Technology, Frederiksborgvej 399, 4000, Roskilde, Denmark.
Background: Brachytherapy (BT) is routinely used in the treatment of various cancers. Current BT relies on the placement of large sources of radioactivity at the tumor site, requiring applicators that may cause local traumas and lesions. Further, they suffer from inflexibility in where they can be placed and some sources reside permanently in the body, causing potential long-term discomfort.
View Article and Find Full Text PDFFunctionalization of layered double hydroxides on bentonite for cesium and iodine retention in high-level radioactive waste disposal.
Chemosphere
February 2025
Division of Advanced Nuclear Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, South Korea; Division of Environmental Science & Engineering, POSTECH, 77, Cheongam-ro, Nam-gu, Pohang, South Korea. Electronic address:
Bentonite is regarded as an adequate buffer material in deep geological repositories and its swelling properties serve to prevent the penetration of groundwater into the repository and to minimize the release of radionuclides. However, bentonite is rarely effective in removing anionic radionuclides due to its permanent negative surface charge. The aim of this study was to enhance the anion removal ability of bentonite by incorporating layered double hydroxides (LDH) with a high anion exchange capacity.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!