Effect of calcium-based sorbents on the reduction of chlorinated contaminants during municipal solid waste thermal treatment.

Chlorinated contaminants are a cause of significant concern in the development of municipal solid waste (MSW) thermal treatment techniques. This study investigates the efficacy of two calcium (Ca)-based in-furnace additives, calcium oxide (CaO), and calcined dolomite (CD), at reducing the levels of chlorinated contaminants during MSW thermal treatment. The results reveal that Ca-based additives could effectively reduce the chlorine (Cl) content by more than 76.8% and 37.3% in the gas and tar phases, respectively. The total concentration and the international total equivalent (I-TEQ) value of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzo-p-furans (PCDD/Fs) were significantly higher under the incineration condition than pyrolysis and gasification conditions. Adding CaO could reduce the total concentration and the I-TEQ value of PCDD/Fs by more than 43.4% and 36.7%, respectively. The reduction effect on PCDD/Fs was more significant in the gaseous phase and the tar phase than the solid phase. CD was more effective than CaO at reducing the chlorinated contaminants, including hydrogen chloride, Cl in the tar phase, and PCDD/Fs. Thus, adding Ca-based sorbents in the furnace during MSW pyrolysis and gasification can effectively reduce PCDD/Fs generation. Based on the experimental results, the mechanism of Ca-based sorbents on the high-temperature homogeneous reaction of PCDD/Fs formation was analysed.