AI Article Synopsis
- The addition of donor-type groups to allene structures allows the creation of metal coordination complexes, which can interact with both the metal and the allene double bond system.
- These allene-containing metal complexes have potential applications in catalysis and biological interactions due to their unique three-dimensional structures and dual functionality.
- Bis(pyridyl)allenes are highlighted for their robust properties as ligands in new Pd(II), Pt(IV), and Au(III) complexes, showing promise in both catalytic reactions and as antimicrobial and anticancer agents, paving the way for future research in metallodrugs.
Article Abstract
The incorporation of donor-type substituents on the allene core opens up the possibility of coordination complexes in which the metal is bonded to the donor groups, with or without interaction with the double bond system. Despite the challenges in the synthesis of such allene-containing metal complexes, their unique 3D environments and dual functionality (allene and metal) could facilitate catalysis and interaction with chemical and biological systems. Bis(pyridyl)allenes are presented here as robust ligands for novel Pd(II), Pt(IV) and Au(III) complexes. Their synthesis, characterisation and first application as catalysts of benchmark reactions for Pd, Pt and Au are presented with interesting reactivity and selectivities. The complexes have also been probed as antimicrobial and anticancer agents with promising activities, and the first studies on their unusual interaction with several DNA structures will open new avenues for research in the area of metallodrugs with new mechanisms of action.
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