Risk assessment of lead and cadmium leaching from solidified/stabilized MSWI fly ash under long-term landfill simulation test.

The long-term effectiveness concern of municipal solid waste incineration (MSWI) fly ash (FA) disposal has been placed more emphatic recently, however, few studies worked on the control of leaching risk of heavy metals under the long-term stability. In this study, the leaching properties and risk assessment of two representative solidified/stabilized (S/S) FA wastes, i.e., sodium dithiocarbamate (DTC) chelator treated and Portland cement + chelator combining treated, were evaluated by a long-term cycles assessment method which coupled multifaceted environmental stresses (e.g., freezing-thawing, drying-wetting, accelerated carbonation). The results showed that the cement/chelator had a better long-term stability and exhibited ~55% lower cumulative overall pollution toxicity index (OPTI) than chelator treatment after the test, which was always rated as "low risk" during the cycles. In addition, the cement/chelator exhibited ~23.3% smaller cumulative mass release rate than the chelator treatment after 6 cycles and restrained the transformation of Pb and Cd from stable states to removable fractions, which attributes to its great erosion resistance and compact pore structure. Under the cumulative external factors and carbon dioxide attacks, the decalcification of hydrate products (e.g., C-S-H, hydrocalumite), as well as deterioration of pore structure are the critical factors increasing the local erosion, cracking and heavy metals release. Thus, the optimization of S/S waste microstructure (e.g., enhancing binder system) and landfill site conditions (e.g., reducing rainfall impact) could be propitious to the S/S waste risk control and management.