This research studies the physical, superhydrophobic, and optical properties of functionalized silica-coated copper phthalocyanine (CuPc) pigments. The silica coating was confirmed by the size increase and the atomic ratio of silicon and copper of the coated pigments. Under optimal conditions, the green and blue shades of the pigments were enhanced as indicated by the increase in solar reflectance at 450-540 nm for the CuPc green and 380-520 nm for the CuPc blue. The total near-infrared (NIR) reflectance of the CuPc green and blue also increases by 10.6 and 11.5% compared to the uncoated pigments, respectively. The functionalized silica layer also adds a superhydrophobic property to the pigments. The contact angles of the functionalized pigments with water and oil are 154.4 and 54.3° for the CuPc green pigment and 142.9 and 78.1° for the CuPc blue pigment, respectively. The improved optical and hydrophobic properties make the pigment suitable for outdoor applications as an advanced protection layer to slow down material degradations from heat and humidity.
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http://dx.doi.org/10.1021/acsomega.1c03333 | DOI Listing |
Sci Rep
November 2024
Jiangxi Provincial Key Laboratory of Low-Carbon Solid Waste Recycling, School of Geography and Environmental Engineering, Gannan Normal University, Ganzhou, 341000, P. R. China.
Based on the experimentally reported stable and conductive two-dimensional covalent organic frameworks with copper phthalocyanine (CuPc) as building block and cyan substituted phenyl as connector (CuCOF-CN) as an electrocatalyst for CO reduction reaction (RR), first principle calculations were performed on CuCOF-CN and its analog with the CN being replaced by H (CuCOF). Comparatively studied on the crystal structures, electronic properties, and CORR performance of the two catalysts found that CuCOF has reduced crystal unit size, more positive charge on Cu and CuPc segments, smaller band gap, and lower reaction barrier for CO RR than CuCOF-CN. CuCOF is proposed to be good potential electrocatalyst with good environment friendliness.
View Article and Find Full Text PDFAdv Sci (Weinh)
August 2024
Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Institute of Electronic Paper Displays, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou, 510006, P. R. China.
Guided nanowires grown on polymer surfaces facilitate their seamless integration as flexible devices without post-growth processing steps. However, this is challenging due to the inability of polymer films to provide the required lattice-matching effect. In this work, this challenge is addressed by replicating highly aligned nanogrooves from a compact disc (CD) onto a casted flexible polydimethylsiloxane (PDMS) surface.
View Article and Find Full Text PDFChemSusChem
March 2024
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
Efficient electrochemical CO reduction reaction (ECORR) to multi-electron reductive products remains a great challenge. Herein, molecular engineering of copper phthalocyanines (CuPc) was explored by modifying electron-withdrawing groups (EWGs) (cyano, sulfonate anion) and electron-donating groups (EDGs) (methoxy, amino) to CuPc, then supporting onto carbon paper or carbon cloth by means of droplet coating, loading with carbon nanotubes and coating in polypyrrole (PPy). The results showed that the PPy-coated CuPc effectively catalysed ECORR to CH.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
May 2023
Department of Physics and Astronomy, Vrije Universiteit Amsterdam, De Boelelaan 1081, 1081 HV Amsterdam, Netherlands.
Temperature measurements at the nanoscale are vital for the application of plasmonic structures in medical photothermal therapy and materials science but very challenging to realize in practice. In this work, we exploit a combination of surface-enhanced Raman spectroscopy together with the characteristic temperature dependence of the Raman peak maxima observed in β-phase copper phthalocyanine (β-CuPc) to measure the surface temperature of plasmonic gold nanoparticles under laser irradiation. We begin by measuring the temperature-dependent Raman shifts of the three most prominent modes of β-CuPc films coated on an array of Au nanodisks over a temperature range of 100-500 K.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2022
Australian Centre for Advanced Photovoltaics (ACAP), School of Photovoltaic and Renewable Energy Engineering, University of New South Wales, Sydney, NSW 2052, Australia.
Copper (Cu) is present not only in the electrode for inverted-structure halide perovskite solar cells (PSCs) but also in transport layers such as copper iodide (CuI), copper thiocyanate (CuSCN), and copper phthalocyanine (CuPc) alternatives to spiro-OMeTAD due to their improved thermal stability. While Cu or Cu-incorporated materials have been effectively utilized in halide perovskites, there is a lack of thorough investigation on the direct reaction between Cu and a perovskite under thermal stress. In this study, we investigated the thermal reaction between Cu and a perovskite as well as the degradation mechanism by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Kelvin probe force microscopy (KPFM).
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