The moso bamboo fiber powder was used as raw material to prepare cellulose nano-fibril films, 5% of polyvinyl alcohol solution was used as a structural reinforcement agent, dopamine hydrochloride (DA) was used as a surface adhesive, and hexadecyl trimethoxy silane was used as a surface modifier. The superhydrophobic films were prepared by vacuum filtration and impregnation. The results showed that the water contact angle on the surface of the film could reach 156°. The microstructure and chemical composition of the film surface was further studied by scanning electron microscopy (SEM), Fourier transforms infrared spectroscopy (FTIR), and roughness measurement The scanning electron microscopy images showed that the nanofibers on the surface of Cellulose nanofibers film were arranged and randomly distributed, thus forming a dense network interwoven structure. In PDA hydrophobic modification solution, an Hexadecyltrimethoxysilane was hydrolyzed to a hexadecyl silanol to obtain the polar terminal hydroxyl of Hexadecyl silanol molecule. The -OCH3 terminal group of HDTMS reacted with hydroxyl/HO to form a silanol (Si-OH) bond and further condensed to form a Si-O-Si network. In addition, due to the hydrophilicity of the surface of the nano cellulose film, a large amount of-OH was adsorbed on the surface of the nano cellulose film, resulted in the chemical connection between cetyl groups, thus realized the grafting of cetyl long-chain alkyl groups onto the fibers of the nano cellulose film.The film showed good self-cleaning and waterproof properties, which can be widely used in wet environment packaging and building.
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http://dx.doi.org/10.3389/fbioe.2021.756839 | DOI Listing |
Int J Biol Macromol
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University, Nanjing 210037, China; International Innovation Center for Forest Chemicals and Materials, Nanjing Forestry University, Nanjing 210037, China. Electronic address:
Harnessing ionic gradients to generate electricity has inspired the development of nanofluidic membranes with charged nanochannels for osmotic energy conversion. However, achieving high-performance osmotic energy output remains elusive due to the trade-off between ion selectivity and nanochannel membrane permeability. In this study, we report a homogeneous nanofluidic membrane, composed of sulfonated nanoporous carbon (SPC) and TEMPO-oxidized cellulose nanofibers (T-CNF), engineered to overcome these limitations.
View Article and Find Full Text PDFNano Lett
January 2025
Key Laboratory of Advanced Structural Materials, Ministry of Education, and School of Materials Science and Engineering, Changchun University of Technology, Changchun 130012, China.
The growing market for sodium-ion batteries has stimulated interest in research on Prussian blue-type cathode materials. Iron hexacyanoferrate (FeHCF) is considered a desirable Prussian blue-type cathode, but the incomplete electrochemical property of its low-spin iron sites hinders its further practical application. In this paper, carboxymethyl cellulose is demonstrated to have an appropriate binding energy through DFT calculations, synthesize Prussian blue in situ, balance Fe and water in FeHCF, and introduce Fe vacancies to activate low-spin Fe sites.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Department of Soil Science and Agricultural Chemistry, Engineering Polytechnic School, University of Santiago de Compostela, 27002, Lugo, Spain.
The primary goal of the current work was to construct pH-sensitive nano and microcomposite hydrogel beads based on alginate (AL), carboxymethyl cellulose (CMC), biochar (BC), and two Moroccan clays: Ghassoul (swelling SW) and red (not swelling NSW) nano and microhybrid. The adsorbents, SW + AL, SW + AL + BC, SW + AL + CMC, NSW + AL, NSW + AL + BC, NSW + AL + CMC, AL, and AL + CMC were prepared for the adsorption of the antibiotic sulfadiazine (SDZ). The test samples were characterized using a variety of techniques, including X-Ray Diffraction (XRD), IR spectroscopy (FT-IR), and scanning electron microscopy (SEM), with the molecular structures of the studied additives geometrically optimized using the DFT/B3LYP method and the function 6-311G(d).
View Article and Find Full Text PDFCarbohydr Polym
March 2025
Department of Polymer Engineering, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Republic of Korea. Electronic address:
The global challenge of wastewater contamination, especially from persistent pollutants like radioactive isotopes and heavy metals, demands innovative purification solutions. Radioactive iodine isotopes (I and I), stemming from nuclear activities, pose serious health risks due to their mobility, bioaccumulation, and ionizing radiation, particularly impacting thyroid health. Similarly, hexavalent chromium, Cr(VI), is highly toxic and persistent in water, linked to cancer and other severe health issues.
View Article and Find Full Text PDFACS Nano
January 2025
Université Toulouse III Paul Sabatier, CIRIMAT, UMR-CNRS 5085, Toulouse Cedex 9 31062, France.
The rising demand for energy storage calls for technological advancements to address the growing needs. In this context, sodium-ion (Na-ion) batteries have emerged as a potential complementary technology to lithium-ion batteries (Li-ion). Among other materials, NaV(PO)F (NVPF) is a promising cathode for Na-ion batteries due to its high operating voltage and good energy density.
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