Of the pentanitrogen cation (N ) family, the only experimentally known isomer is the V-shaped structure 01. Here, we showed that a super-high-energy (∼100 kcal/mol above 01) all-nitrogen spiropentadiene 02 with considerable σ-delocalization deserves pursuit as the first spirocyclic all-nitrogen molecule, at least spectroscopical.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1063/5.0070369 | DOI Listing |
Publication Analysis
Top Keywords
all-nitrogen spiropentadiene-n
4
spiropentadiene-n pentanitrogen
4
pentanitrogen cation
4
cation family
4
family experimentally
4
experimentally isomer
4
isomer v-shaped
4
v-shaped structure
4
structure super-high-energy
4
super-high-energy ∼100
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!