Trace holmium assisting delaminated OMS-2 catalysts for total toluene oxidation at low temperature.

In this study, octahedral molecular sieve (OMS-2) is successfully delaminated by using trace holmium (Ho) via a facile redox co-precipitation route, which exhibits high performance for the total toluene oxidation at low temperature. High resolution transmission electron microscope (HRTEM), X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) analyses verify that abundant multi-phase interfaces and lattice dislocations are formed on the obtained delaminated OMS-2 by the Ho (Ho-OMS-2), which can induce more active oxygen species. In particular, the delaminated OMS-2 with a trace Ho amount has a high O/O ratio with a balanced ratio of Mn and Mn, demonstrating much higher activity (T of 228 °C even under 5 vol% HO vapor over 0.5% Ho-OMS-2) than the parent OMS-2 (T of 261 °C) for the total toluene oxidation. Furthermore, the positive effect of the introduction of HO on catalytic activity, especially the enhancement of the conversion of intermediates into CO and HO, is verified by the in situ diffuse reflection infrared Fourier transform spectroscopy (DRIFTS). Based on these results, the reaction mechanism for toluene oxidation over the OMS-2 based catalyst is proposed. It is expected to provide an effective preparation method to obtain high-performance catalysts for the VOCs oxidation at low temperatures.