Combinations of best management practices (BMPs) are needed to achieve nutrient reduction goals in the Mississippi/Atchafalaya River Basin (MARB), but field results are crucial to encourage stacked adoption of BMPs. A paired catchment-scale study (2015-18) was done to assess the impact of (i) BMPs, (ii) precipitation patterns, and (iii) seasonality on nitrogen (N) export. Flow-weighted samples were collected and analyzed for total ammonia nitrogen (TAN), nitrate (NO-N), and total nitrogen (TN). Catchments Low-BMP 11 and High-BMP 12 had 27.6% and 87.6% areal coverage of BMPs, respectively. No significant difference (p > 0.05) in TAN concentrations was found between Low-BMP 11 (0.023 mg L) and High-BMP 12 (0.020 mg L). However, NO-N and TN concentrations were significantly higher (p < 0.05) at Low-BMP 11 (NO-N: 26.0 mg L, TN: 28.7 mg L) than at High-BMP 12 (NO-N: 8.8 mg L, TN: 9.2 mg L). Two precipitation factors that affected N export patterns were observed. First, N flushing could continue for several years after a drought as elevated NO-N concentrations were observed in 2015 (i.e., two years after the 2011-2013 drought). Second, higher annual N export was observed when more precipitation occurred during the pre-planting or early-growing season versus later periods. For both catchments, the highest 50% of flows were responsible for majority of the NO-N export. We estimated that 33-37%, 61-62%, and 82-85% of the NO-N loads occurred in the 90th, 75th, and 50th flow percentiles, respectively. As demonstrated in High-BMP 12, stacked BMP application effectively lowered NO-N and TN loads by 60.3% and 59.1%, respectively, relative to Low-BMP 11. Although 27.6% BMP coverage area in Low-BMP 11 was considered low for this study, this coverage area is higher than many other parts of the MARB. This research highlights the importance of joint efforts between landowners in a watershed to meet downstream water quality goals.
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http://dx.doi.org/10.1016/j.jenvman.2021.114053 | DOI Listing |
Conserv Biol
January 2025
Marine Mammal Research Program, Hawai'i Institute of Marine Biology, University of Hawai'i at Mānoa, Kāne'ohe, Hawai'i, USA.
Several legal acts mandate that management agencies regularly assess biological populations. For species with distinct markings, these assessments can be conducted noninvasively via capture-recapture and photographic identification (photo-ID), which involves processing considerable quantities of photographic data. To ease this burden, agencies increasingly rely on automated identification (ID) algorithms.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
School of Materials and Energy, University of Electronic Science and Technology of China, Chengdu 611731, China.
The utilization of carbide slag, an industrial by-product, as a resource to prepare value-added products has a profound impact not only for sustainable synthesis and the circular economy but also for CO reduction. Herein, we report the very first example of the controlled multi-dimensional assembly of calcium carbonate particles at the micrometer scale with industrial by-product carbide slag and CO. Calcium carbonate particles of distinctly different sizes, shapes, and morphologies are obtained by finely tuning the assembly conditions.
View Article and Find Full Text PDFJ Acoust Soc Am
December 2024
Department of Mechanical and Aerospace Engineering, Rutgers University, Piscataway, New Jersey 08854, USA.
This study introduces a general analytical model designed to predict the sound reduction frequency of side-branch resonators, regardless of their geometric shapes. Grounded in a continuous analogy mass-spring system, we conceptualize the air within the branch cavity of the resonator as a series of infinitesimal continuous air layers. Each air layer is represented as a mass-spring unit, influenced by the pressure distribution inside the branch cavity.
View Article and Find Full Text PDFOrg Biomol Chem
December 2024
Department of Chemistry & Biochemistry, Texas Christian University, Fort Worth, TX 76129, USA.
Modifying the backbone of 24-atom macrocycles allows tailoring of physical properties (octanol-water partition coefficients, log ) while conserving both conformation and the barrier to dynamic, hinge-like motion. Structure is determined by 1D and 2D NMR spectroscopy. The barrier can be subtly tuned by modifications that appear to preclude fully revolute motion and efficient π-stacking of the two subunits.
View Article and Find Full Text PDFbioRxiv
December 2024
Department of Biochemistry & Molecular Biophysics, Columbia University Irving Medical Center, New York, NY, 10032, USA.
Most eukaryotes possess two Rad51/RecA family DNA recombinases that are thought to have arisen from an ancient gene duplication event: Rad51, which is expressed in both mitosis and meiosis; and Dmc1, which is only expressed in meiosis. To explore the evolutionary relationship between these recombinases, here, we present high-resolution CryoEM structures of Rad51 filaments and Dmc1 filaments bound to ssDNA, which reveal a pair of stacked interfacial aromatic amino acid residues that are nearly universally conserved in Rad51 but are absent from Dmc1. We use a combination of bioinformatics, genetic analysis of natural sequence variation, and deep mutational analysis to probe the functionally tolerated sequence space for these stacked aromatic residues.
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