Motivated by the recent experimental discovery of high-temperature carbonaceous sulfur hydride (C-S-H), we have systematically explored the superconductivity of a carbonaceous lanthanum hydride (C-La-H) ternary compound in the pressure range of 50-250 GPa. Based on first-principles calculations and strong-coupling Migdal-Eliashberg theory, we find that a hitherto unreported LaCH ternary system is dynamically and thermally stable above 70 GPa in a clathrate structure with space group 3̄ and exhibits a superconducting critical temperature, , in the range of 69-140 K.
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ACS Omega
December 2024
Research Center for Advanced Computing Infrastructure, JAIST, 1-1 Asahidai, Nomi 923-1211, Ishikawa, Japan.
There has been a marked increase in interest in high-temperature superconductors over the past few years, sparked by their potential to revolutionize multiple fields, including energy generation and transportation. A particularly promising avenue of exploration has emerged in the form of ternary superhydrides, compounds composed of hydrogen along with two other rare-earth elements. Our investigation focuses on the search for Y-Th-H ternary compounds; employing an evolutionary search methodology complemented by electron-phonon calculations reveals a stable superhydride, 6̅2-YThH, capable of exhibiting a critical temperature ( ) as high as 222 K at 200 GPa along a few low- novel hydrides.
View Article and Find Full Text PDFNatl Sci Rev
July 2024
Key Laboratory of Material Simulation Methods & Software of Ministry of Education, College of Physics, Jilin University, Changchun 130012, China.
Room-temperature superconductivity has been a long-held dream of mankind and a focus of considerable interest in the research field of superconductivity. Significant progress has recently been achieved in hydrogen-based superconductors found in superhydrides (hydrides with unexpectedly high hydrogen contents) that are stabilized under high-pressure conditions and are not capturable at ambient conditions. Of particular interest is the discovery of a class of best-ever-known superconductors in clathrate metal superhydrides that hold the record for high superconductivity (e.
View Article and Find Full Text PDFNature
March 2024
Department of Physics, University of California, Berkeley, CA, USA.
By directly altering microscopic interactions, pressure provides a powerful tuning knob for the exploration of condensed phases and geophysical phenomena. The megabar regime represents an interesting frontier, in which recent discoveries include high-temperature superconductors, as well as structural and valence phase transitions. However, at such high pressures, many conventional measurement techniques fail.
View Article and Find Full Text PDFNat Commun
February 2024
Department of Physics and Texas Center for Superconductivity, University of Houston, Houston, TX, 77204, USA.
Further increasing the critical temperature and/or decreasing the stabilized pressure are the general hopes for the hydride superconductors. Inspired by the low stabilized pressure associated with Ce 4f electrons in superconducting cerium superhydride and the high critical temperature in yttrium superhydride, we carry out seven independent runs to synthesize yttrium-cerium alloy hydrides. The synthetic process is examined by the Raman scattering and X-ray diffraction measurements.
View Article and Find Full Text PDFNatl Sci Rev
January 2024
School of Physical Science and Technology, Ningbo University, Ningbo315211, China.
As compressed hydrides constantly refresh the records of superconducting critical temperatures () in the vicinity of room temperature, this further reinforces the confidence to find more high-temperature superconducting hydrides. In this process, metastable phases of superhydrides offer enough possibilities to access superior superconducting properties. Here we report a metastable hexagonal lanthanum superhydride (6-LaH) stabilized at 146 GPa by introducing an appropriate proportion of Al, which exhibits high-temperature superconductivity with ∼ 178 K, and this value is enhanced to a maximum ∼ 223 K at 164 GPa.
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