Herein, a new organic-inorganic hybrid cuprous iodide of [(Me)-DABCO]CuI was prepared and structurally characterized with a novel three-dimensional (3D) [CuI] framework. Significantly, this 3D cuprous iodide displays infrequent broadband red-to-near-infrared light emission (600-1000 nm) stemming from the radiative recombination of self-trapped excitons.
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http://dx.doi.org/10.1021/acs.inorgchem.1c02330 | DOI Listing |
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