One of the important research directions in pulse power technology is to increase power density and operational stability of compact high-power pulse transformers. In this paper, the research object is a high-power pulse transformer using combined insulation, and the operating characteristics are obtained using simulation and experiment methods. The experimental results show that the maximum output voltage of the transformer increases by 30% in the combined insulation. At the same time, the combined insulation transformers are safer and have better insulation holding capacity. Moreover, multiple breakdowns have less effect on the subsequent breakdown voltage of the combined insulation transformer. The average subsequent breakdown voltage after 30 breakdowns of combination insulated transformers is still higher than the first breakdown voltage of non-combined insulation transformers. In addition, the energy storage density of combined insulation transformers is ∼40% higher than that of non-combined insulation transformers because of the higher permittivity of Midel 7131 than transformer oil.
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Adv Mater
January 2025
Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China.
Achieving optimal capacitive energy storage performance necessitates the integration of high energy storage density, typical of ferroelectric dielectrics, with the low polarization loss associated with linear dielectrics. However, combining these characteristics in a single dielectric material is challenging due to the inherent contradictions between the spontaneous polarization of ferroelectric dielectrics and the adaptability of linear dielectrics to changes in the electric field. To address this issue, a linear isotactic sulfonylated polynorbornene dielectric characterized by ferroelectric-like crystals has been developed.
View Article and Find Full Text PDFSci Rep
January 2025
Astronomical Observatory, Jagiellonian University, Orla 171, Krakow, 30-244, Poland.
The single crystals of lead-free NaBiTiO were grown using the Czochralski method. The energy gaps determined from X-ray photoelectron spectroscopy (XPS) and optical measurements were approximately 2.92 eV.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Materials Department, University of California, Santa Barbara, Santa Barbara, California 93106, United States.
The insulating transition metal nitride CaCrN consists of sheets of triangular [CrN] units with symmetry that are connected via quasi-1D zigzag chains. Due to strong covalency between Cr and N, Cr ions are unusually low-spin, and = 1/2. Magnetic susceptibility measurements reveal dominant quasi-1D spin correlations with very large nearest-neighbor antiferromagnetic exchange = 340 K and yet no sign of magnetic order down to = 0.
View Article and Find Full Text PDFNanoscale
January 2025
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Ammonium perchlorate (AP) is widely utilized in aerospace, defense and other fields due to its high energy density, exceptional stability, easy availability and adaptability. However, the high sensitivity and hygroscopicity of AP severely constrain its application in numerous fields. In this study, a two-step continuous coating method was employed to construct AP-based energetic microcapsules with low sensitivity and hygroscopicity.
View Article and Find Full Text PDFACS Omega
January 2025
Department of Chemistry, Banaras Hindu University, Varanasi, Uttar Pradesh 221005, India.
The ZrO-embedded carboxy-functionalized -BN composite, combined with graphene oxide (GO), formed a novel BN-COOH@ZrO/GO composite. Structural characterization through IR, Raman spectroscopy, powder X-ray diffraction, and X-ray photoelectron spectroscopy supported the successful preparation of the composite, while scanning electron microscopy and transmission electron microscopy revealed its surface morphology and the presence of component materials. UV-vis spectroscopy (solid state) further supported these findings.
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