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Development of diselenide-based fluorogenic system for the selective and sensitive detection of the Hg(II) in aqueous media.
Dalton Trans
January 2025
Department of Chemistry, University of Mumbai, Mumbai, 400098, India.
Mercury(II) is highly toxic thus the selective and sensitive detection of Hg(II) is important. This research article deals with the synthesis and characterization of the fluorogenic system based on diselenide containing rhodamine by single crystal XRD. The probe has been used for selective detection of Hg(II) in aqueous media with detection limit of 62.
View Article and Find Full Text PDFClinicopathological and in Silico Insights into Male Infertility: Agerelated Trends and Anti-sperm Antibodies Post COVID-19 Vaccination.
Curr Med Chem
January 2025
Department of Biochemistry, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia.
Background: Infertility was often considered a female issue, but male infertility emerged significantly after the Covid-19 pandemic. Hence, assessments are crucial for planning policies on health care and family planning and reasons thereof post vaccinations.
Material And Methods: The present study was a case-control, dual-centers, prospective study with normal sperm parameters.
Amputees but not healthy subjects optimally integrate non-spatially matched visuo-tactile stimuli.
iScience
January 2025
Laboratory for Neuroengineering, Department of Health Science and Technology, Institute for Robotics and Intelligent Systems, ETH Zürich, 8092 Zürich, Switzerland.
Our brain combines sensory inputs to create a univocal perception, enhanced when stimuli originate from the same location. Following amputation, distorted body representations may disrupt visuo-tactile integration at the amputated leg. We aim to unveil the principles guiding optimal and cognitive-efficient visuo-tactile integration at both intact and amputated legs.
View Article and Find Full Text PDFReinforcing Bulk Heterojunction Morphology through Side Chain-Engineered Pyrrolopyrrole-1,3-dione Polymeric Donors for Nonfullerene Organic Solar Cells.
ACS Appl Energy Mater
January 2025
School of Advanced Materials Science and Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea.
Organic solar cells (OSCs) are attracting significant attention due to their low cost, lightweight, and flexible nature. The introduction of nonfullerene acceptors (NFAs) has propelled OSC development into a transformative era. However, the limited availability of wide band gap polymer donors for NFAs poses a critical challenge, hindering further advancements.
View Article and Find Full Text PDFBinary Catalyst Manipulating the Sequences of Poly(ester-carbonate) Copolymers in Metal-Free Terpolymerization of Epoxide, Anhydride, and CO.
Precis Chem
January 2025
Key Laboratory of Biobased Polymer Materials, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
The one-pot terpolymerization of epoxide (EP), anhydride (AH), and CO to synthesize polyester-polycarbonate copolymers with precise sequences remains a significant challenge in polymer chemistry. In this study, promising progress was achieved by utilizing a cyclic trimeric phosphazene base (CTPB) and triethylboron (TEB) as a binary catalyst, enabling the synthesis of both well-defined block and truly random poly(ester-carbonate) copolymers through the one-pot terpolymerization of EP/AH/CO. By adjusting the molar ratio of CTPB/TEB to 1/0.
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