The mineralising effect of CuO on microstructure and phase composition of SO -doped clinker was studied by a combination of phase analysis, light and scanning electron microscopy and QXRD. Results show proportionally higher C AF content in clinker interstitial matter due to CuO doping. CuO also lowers the SO incorporation in main clinker phases C S and C S. Observation in back-scattered electrons revealed that Cu crystallises mainly as a Cu-rich phase in the clinker interstitial matter and inclusions in crystals of C S with distorted structure. CuO partially inhibits the incorporation of Fe O in C S.
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http://dx.doi.org/10.1111/jmi.13069 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
Department of Mechanical and Mechatronics Engineering, University of Waterloo, 200 University Ave W, Waterloo, Ontario N2L 3G1, Canada.
Despite the potential of nanoenergetics as promising energy sources with high energy densities and fast energy release, our limited ability to predict combustion speeds restricts the utilization of nanoenergetics. Here, we provide a comprehensive analysis of thermal microstructures subject to heterogeneous reactions and propose a new scaling for combustion wave speeds. To control reaction heterogeneity, two different particle interfacial morphologies of physically mixed and core-shell Al/CuO nanoparticles were synthesized.
View Article and Find Full Text PDFJ Phys Condens Matter
November 2024
Department of Pure and Applied Physics, Guru Ghasidas University (A Central University) Koni, Bilaspur, Chattisgarh 495 009, India.
We report the synthesis and characterization of pure CuO and CuO-ZnO nanostructured composite thin films sprayed on particle-free glass substrates using chemical spray pyrolysis method. The films were systematically analyzed through microstructural, morphological, chemical, and gas-sensing studies. X-ray diffraction (XRD) studies confirmed the polycrystalline nature of the films, with a predominant monoclinic phase along the (002) direction.
View Article and Find Full Text PDFSmall
December 2024
School of Physics and Electronics, Key Laboratory of Low-dimensional Quantum Structures and Quantum Control of the Ministry of Education, Synergetic Innovation Center for Quantum Effects and Applications, Institute of Interdisciplinary Studies, Key Laboratory for Matter Microstructure and Function of Hunan Province, Hunan Normal University, Changsha, Hunan, 410081, China.
Chemodynamic therapy (CDT) is emerged as a novel and promising tumor therapy by using the powerful reactive oxygen species (ROS) to kill cancer cells. However, the current CDT is remarkably inhibited due to insufficient HO supply and over-expression of glutathione (GSH) in the tumor microenvironment (TME). Herein, a biodegradable self-supplying HO nano-enzyme of CuO@CaP with a GSH-consumption effect is designed for cascade enhanced CDT to overcome the problem of HO deficiency and GSH overexpression.
View Article and Find Full Text PDFSci Rep
October 2024
Chair and Department of Biochemistry and Biotechnology, Medical University of Lublin, Lublin, 20-400, Poland.
This study is the first one that investigates in detail the bacterial intercellular response to the high density of crystallographic defects including vacancies created in Cu by high pressure torsion. To this aim, samples were deformed by high pressure torsion and afterward, their antibacterial properties against Staphylococcus aureus were analyzed in adhesion tests. As a reference an annealed sample was applied.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2024
CNRS, Université de Poitiers, Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP) (ENSI-Poitiers), B1, 1 rue Marcel Doré, 86073, Poitiers, France.
Efficient energy transfer management in catalytic processes is crucial for overcoming activation energy barriers while minimizing costs and CO emissions. We exploit here a concept of CuO particle design with multiple gas-stabilizing sites, engineered to function as cavitation nuclei and catalysts. This concept facilitates the selective and efficient acoustic energy transfer directly to the catalyst surface, avoiding the undesired dissipation of acoustic energy into the bulk solution while demonstrating superior cavitation properties at lower acoustic pressure amplitudes.
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