Electrodeposition of Pb and PbO on Graphite Felt in Membraneless Flow-Through Reactor: A Method to Prepare Lightweight Electrode Grids for Lead-Acid Batteries.

Materials (Basel)

Department of Physical and Inorganic Chemistry, Faculty of Chemical Technology, Kaunas University of Technology, Radvilėnų pl. 19, 50254 Kaunas, Lithuania.

Published: October 2021

One of the possible ways of mitigating the primary lead-acid battery downside-mass- is to replace the heavy lead grids that can add up to half of the total electrode's mass. The grids can be exchanged for a lightweight, chemically inert, and conductive material such as graphite felt. To reduce carbon surface area, Pb/PbO can be electrochemically deposited on graphite felt. A flow-through reactor was applied to enhance penetration of adequate coverage of graphite felt fibers. Three types of electrolytes (acetate, nitrate, and methanesulfonate) and two additives (ligninsulfonate and Triton X-100) were tested. The prepared composite electrodes showed greater mechanical strength, up to 5 times lower electrical resistivity, and acted as Pb and PbO electrodes in sulfuric acid electrolytes.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8537699PMC
http://dx.doi.org/10.3390/ma14206122DOI Listing

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