Spun concrete technology allows manufacturing the reinforced concrete poles, piles, and columns with a circular hollow core. This concreting method ensures higher concrete density and strength than the traditional vibration technique and self-compacting concrete. This technology defines an attractive alternative for producing steel-concrete composite elements, allowing efficient utilisation of the materials due to the confinement effect. This study experimentally investigates the material behaviour of the composite columns subjected to axial compression. The experimental results support the above inference-the test outcomes demonstrate the 1.2-2.1 times increase of the compressive strength of the centrifugal concrete regarding the vibrated counterpart; the experimental resistance of the composite columns 1.25 times exceeds the theoretical load-bearing capacity. The proposed mechanical-geometrical parameter can help to quantify the composite efficiency. The parametric analysis employs the finite element model verified using the test results. It demonstrates a negligible bond model effect on the deformation prediction outcomes, indirectly indicating the steel shell confinement effect and confirming the literature results.
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http://dx.doi.org/10.3390/ma14206046 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Zhejiang University, Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, 866 Yuhangtang Road, Xihu District, hangzhou City, 310058, Hangzhou, CHINA.
The separation of xylene isomers is a critical and energy-intensive process in the petrochemical industry, primarily due to their closely similar molecular structures and boiling points. In this work, we report the synthesis and application of a novel core-shell zeolitic imidazolate framework (ZIF) composite, ZIF-65@ZIF-67, designed to significantly enhance the kinetic separation of xylene isomers through a synergistic "shell-gated diffusion and core-facilitated transport" strategy. The external ZIF-67 shell selectively restricts the diffusion of larger isomers (MX and OX), while the internal ZIF-65 core accelerates the diffusion of PX, thereby amplifying the diffusion differences among the isomers.
View Article and Find Full Text PDFAnal Chem
January 2025
Instrumental Analytical Chemistry, University of Duisburg-Essen, Universitätsstraße 5, 45141 Essen, Germany.
Compound-specific stable isotope analysis (CSIA) using liquid chromatography-isotope ratio mass spectrometry (LC-IRMS) is a powerful tool for determining the isotopic composition of carbon in analytes from complex mixtures. However, LC-IRMS methods are constrained to fully aqueous eluents. Previous efforts to overcome this limitation were unsuccessful, as the use of organic eluents in LC-IRMS was deemed impossible.
View Article and Find Full Text PDFPhytochem Anal
January 2025
School of Pharmacy, Shenyang Pharmaceutical University, Shenyang, China.
Objective: This study aimed to qualitatively study the main chemical components of apple peel in APORT, Kazakhstan, by ultra-performance liquid chromatography-quadrupole-time-of-flight mass spectrometry (UPLC-Q-TOF-MS/MS) and to compare the components of apple peels with different provenances.
Methods: An ACQUITY UPLC HSS T3 (100 mm × 2.1 mm, 1.
Sci Total Environ
January 2025
Center for Marine Sensors, Institute for Chemistry and Biology of the Marine Environment (ICBM), Carl von Ossietzky University of Oldenburg, 26382 Wilhelmshaven, Germany.
Microplastics (MP) are known to be ubiquitous. The pathways and fate of these contaminants in the marine environment are receiving increasing attention, but still knowledge gaps exist. In particular, the link between mass-based MP quantification and oceanographic parameters is often lacking.
View Article and Find Full Text PDFSci Total Environ
January 2025
Department of Civil and Environmental Engineering, Temple University, Philadelphia, PA 19122, USA. Electronic address:
This study investigated the regenerability of anion exchange resins for per- and polyfluoroalkyl substances (PFAS), focusing on the interaction between regenerant composition and resin characteristics. The influence of salt type and concentration on PFAS solubility revealed a general decline in perfluorohexane sulfonate (PFHxS) solubility with increased salt concentrations, most strongly with KCl followed by NaCl and NHCl. Mixed solubility results were observed for perfluorooctanoate (PFOA) and perfluorooctane sulfonate (PFOS).
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