The proton battery is a very novel emerging research area with practicability. The proton battery has charging and discharging functions. It not only electrolyzes water: the electrolyzed protons can be stored but also released, which are combined with oxygen to generate electricity, and the hydrogen is not required; the hydrogen ions will be released from the battery. According to the latest document, the multiple important physical parameters (e.g., hydrogen, voltage, current, temperature, humidity, and flow) inside the proton battery are unlikely to be obtained accurately and the multiple important physical parameters mutually influence the data; they have critical effects on the performance, life, and health status of the proton battery. At present, the proton battery is measured only from the outside to indirectly diagnose the health status of battery; the actual situation inside the proton battery cannot be obtained instantly and accurately. This study uses micro-electro-mechanical systems (MEMS) technology to develop a low-temperature micro hydrogen sensor, which is used for monitoring the internal condition of the proton battery and judging whether or not there is hydrogen leakage, so as to enhance the safety.
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http://dx.doi.org/10.3390/mi12101215 | DOI Listing |
Macromol Rapid Commun
December 2024
Department of Chemistry and Industrial Chemistry, University of Pisa, Pisa, 56124, Italy.
This study presents the preparation and electrochemical testing of sulfonated styrene-grafted poly(vinylidene fluoride) (pVDF) copolymers as proton exchange membranes (PEMs) for semi-organic redox flow batteries (RFBs) based on 9,10-anthraquinone-2,7-disulfonic acid (AQDS)/bromine. The copolymers are synthesized via a two-step procedure, involving i) atom transfer radical polymerization of styrene (Sty) for the grafting to the pVDF backbone and ii) the sulfonation of the polystyrene grafted side chains. Copolymers with different amounts of sulfonated styrene (SSty) in the side chains (i.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, China.
Developing highly active and durable non-noble metal catalysts is crucial for energy conversion and storage, especially for proton exchange membrane fuel cells (PEMFCs) and lithium-oxygen (Li-O) batteries. Non-noble metal catalysts are considered the greatest potential candidates to replace noble metal catalysts in PEMFCs and Li-O batteries. Herein, we propose a novel type of non-noble metal catalyst (Fe-Hf/N/C) doped with Hf into a mesoporous carbon material derived from Hf-ZIF-8 and co-doping with Fe and N, which greatly enhanced the activity and durability of the catalyst.
View Article and Find Full Text PDFAdv Mater
December 2024
School of Advanced Materials, Peking University Shenzhen Graduate School, Shenzhen, 518055, China.
Single-crystal high-nickel oxide with an integral structure can prevent intergranular cracks and the associated detrimental reactions. Yet, its low surface-to-volume ratio makes surficial degradation a more critical factor in electrochemical performance. Herein, artificial proton-rich (ammonium bicarbonate) shell is successfully introduced on the nickel-rich LiNiCoMnO single crystals for in situ electrochemically conversing into inorganic maskant to enhance stability of cathode.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
NUAA: Nanjing University of Aeronautics and Astronautics, Material Science and Technology, CHINA.
Proton electrochemistry holds eminent potential for developing high capacity and rate energy storage devices in the post-lithium era. However, the decomposition of water in acidic aqueous electrolytes causes electrode corrosion, leading to capacity fading. Herein, we report a judicious design of molecular micellar aggregates as non-aqueous electrolytes for stable and high-voltage electrochemical proton storage.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
State Key Laboratory of Catalysis-Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China. Electronic address:
Interfacial hydrogen bonds are pivotal in enhancing proton activity and accelerating the kinetics of proton-coupled electron transfer during electrocatalytic oxygen reduction reaction (ORR). Here we propose a novel FeCr bimetallic atomic sites catalyst supported on a honeycomb-like porous carbon layer, designed to optimize the microenvironment for efficient electrocatalytic ORR through the induction of interfacial hydrogen bonds. Characterizations, including X-ray absorption spectroscopy and in situ infrared spectroscopy, disclose the rearrangement of delocalized electrons due to the formation of FeCr sites, which facilitates the dissociation of interfacial water molecules and the subsequent formation of hydrogen bonds.
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