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Cyclotrimerization of Acetylene under Thermal Conditions: Gas-Phase Kinetics of V and Fe + CH. | LitMetric

Cyclotrimerization of Acetylene under Thermal Conditions: Gas-Phase Kinetics of V and Fe + CH.

J Phys Chem A

Air Force Research Laboratory, Space Vehicles Directorate, Kirtland Air Force Base, Albuquerque, New Mexico 87117, United States.

Published: October 2021

AI Article Synopsis

Article Abstract

The kinetics of successive reactions of acetylene (CH) initiated on either vanadium or iron atomic cations have been investigated under thermal conditions using the variable-ion source and temperature-adjustable selected-ion flow tube apparatus. Consistent with the literature results, the reaction of Fe + CH primarily yields Fe(/ = (CH)); however, analysis via quantum chemical calculations and statistical modeling shows that the mechanism does not form benzene upon the third acetylene addition. The kinetics are more consistent with successive addition of three acetylene molecules, yielding Fe(CH), followed by an addition of a fourth acetylene molecule, initiating cyclotrimerization, yielding either Fe(CH) + neutral benzene or Fe(Bz) + acetylene, where Bz is a benzene ligand. In contrast, the reaction of V + CH yields products via successive associations V(/ = (CH)) either with or without a bimolecular step involving loss of one H and VC(/ = (CH)), where and extend at least up to 11 under conditions of 0.32 Torr at 300 K. Stabilized V(Bz) is not a significant intermediate in the association mechanism. We propose a plausible mechanism for the generation of neutral benzene in this reaction and compare with the Fe results. The reaction steps that produce benzene result in turnover of the single-atom catalyst, and the large hydrocarbons produced that remain associated to the catalyst are proposed to be polycyclic aromatic hydrocarbons.

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Source
http://dx.doi.org/10.1021/acs.jpca.1c06439DOI Listing

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