A new noncentrosymmetric iron-iodate-fluoride Ba[FeF(IO)]IO was ingeniously obtained based on the centrosymmetric Ba[FeF(IO)] through chemical tailoring. Ba[FeF(IO)]IO exhibits a strong phase-matchable second-harmonic generation effect, a large band gap, and a wide mid-infrared transparent window. The chemical tailoring design based on oxide-fluoride anions affords a feasible approach to design nonlinear optical materials.
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| http://dx.doi.org/10.1039/d1cc04462a | DOI Listing |
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