Globally, millions of people have no access to clean drinking water and are either striving for that or oppressed to intake polluted water. Arsenic is considered one of the most hazardous contaminants in water bodies that reaches there due to various natural and anthropogenic activities. Modified chitosan has gained much attention from researchers due to its potential for arsenic removal. This review focuses on the need and potential of chitosan-based biosorbents for arsenic removal from water systems. Chitosan is a low-cost, abundant, biodegradable biopolymer that possesses unique structural aspects and functional sites for the adsorption of contaminants like arsenic species from contaminated water. The chitosan-based biosorbents had also been modified using various techniques to enhance their arsenic removal efficiencies. This article reviews various forms of chitosan and parameters involved in chitosan modification which eventually affect the arsenic removal efficiency of the resultant sorbents. The literature revealed that the modified chitosan-based sorbents could express higher adsorption efficiency compared to those prepared from native chitosan. The sustainability of the chitosan-based sorbents has also been considered in terms of reusability. Finally, some recommendations have been underlined for further improvements in this domain.
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http://dx.doi.org/10.1016/j.ijbiomac.2021.10.050 | DOI Listing |
Materials (Basel)
January 2025
Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 040 01 Košice, Slovakia.
In Slovakia, there are a number of contaminated sites that have occurred due to intensive mining, mineral processing, metallurgical activities, chemical industry, fossil fuel combustion, and industrial agriculture in the past. This paper summarizes the occurrence, chemistry, toxicity, and mineralogy of arsenic species related to soil and water contamination in Slovakia. Four main localities with arsenic exposure were identified.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
John A. Reif, Jr. Department of Civil and Environmental Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, USA.
In this study, synthetic wastewater containing 110 µg/L arsenate (As(V)), 0-20 mg/L fulvic acid (FA), and 0-12.3 mg/L phosphate was treated with 3 mg/L Fe. The mechanisms of FA and phosphate effects on As(V) removal by ferric chloride were determined using 0.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China. Electronic address:
Arsenic-contaminated groundwater is widely used in agriculture. To meet the increasing demand for safe water in agriculture, an efficient and cost-effective method for As removal from groundwater is urgently needed. We hypothesized that Fe (oxyhydr)oxide (FeOOH) minerals precipitated in situ from indigenous Fe in groundwater may immobilize As, providing a solution for safely using As-contaminated groundwater in irrigation.
View Article and Find Full Text PDFWater Res
January 2025
Baohang Environment Co., LTD, Beijing 100070, China. Electronic address:
Iron sulfide (FeS) exhibits superior reactivity toward a wide range of contaminants, making it a promising candidate for environmental remediation in various media, including surface water, wastewater, soil, and groundwater. Driven by green and sustainable development principles, efficient, low-cost, and environmentally friendly biosynthesis has attracted considerable attention and has great environmental remediation potential. This review provides a comprehensive overview of the recent advances in biogenic FeS (bio-FeS), focusing on its synthesis mechanisms, performance characterization, and environmental applications.
View Article and Find Full Text PDFSci Rep
January 2025
Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran.
Co-pyrolysis is an efficient approach for municipal sewage sludge (SS) treatment, facilitating the production of biochar and promoting the stabilization and removal of heavy metals, particularly when combined with chlorinated materials. This study explores the impact of pyrolysis temperatures (400 °C and 600 °C) and chlorinated additives (polyvinyl chloride (PVC) as an organic chloride source and ferric chloride (FeCl) as an inorganic chloride source) at 10% and 20% concentrations, on the yield, chemical speciation, leachability, and ecological risks of arsenic (As), chromium (Cr), and zinc (Zn) in biochar derived from SS. The results revealed that increasing the pyrolysis temperature from 400 to 600 °C significantly reduced biochar yield due to enhanced volatilization of organic components, as well as the removal of heavy metals in interaction with chlorinated materials.
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