Soft glassy materials such as mayonnaise, wet clays, or dense microgels display a solid-to-liquid transition under external shear. Such a shear-induced transition is often associated with a nonmonotonic stress response in the form of a stress maximum referred to as "stress overshoot." This ubiquitous phenomenon is characterized by the coordinates of the maximum in terms of stress σ_{M} and strain γ_{M} that both increase as weak power laws of the applied shear rate. Here we rationalize such power-law scalings using a continuum model that predicts two different regimes in the limit of low and high applied shear rates. The corresponding exponents are directly linked to the steady-state rheology and are both associated with the nucleation and growth dynamics of a fluidized region. Our work offers a consistent framework for predicting the transient response of soft glassy materials upon startup of shear from the local flow behavior to the global rheological observables.
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http://dx.doi.org/10.1103/PhysRevLett.127.148003 | DOI Listing |
Soft Matter
January 2025
Tata Institute of Fundamental Research, Gopanpally Village, Hyderabad-500046, India.
The glass-like slow dynamics in confluent epithelial monolayers is crucial for wound healing, embryogenesis, cancer progression, Experiments have indicated several unusual properties in these systems. Unlike ordinary glasses, the glassiness in cellular systems strongly correlates with their static properties and is sub-Arrhenius. These results imply that the slow dynamics in epithelial monolayers is either not glassy or the underlying mechanism is different from ordinary glasses.
View Article and Find Full Text PDFSci Adv
November 2024
Institut Européen des Membranes, Adaptive Supramolecular, Nanosystems Group, University of Montpellier, ENSCM, CNRS, Place Eugène Bataillon, CC 047, F-34095, Montpellier, France.
The capture of CO is of high interest in our society representing an essential tool to mitigate man-made climate warming. Membrane technology applied for CO capture offers several advantages in terms of energy savings, simple operation, and easy scale-up. Glassy membranes are associated with low gas permeability that negatively affect on their industrial implementation.
View Article and Find Full Text PDFMacromol Rapid Commun
November 2024
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai, 201620, P. R. China.
Living tissues span a remarkable spectrum of modulus ranging from the level of Pa to GPa in a water-rich environment. Constructing soft and hard materials that match the mechanics of tissues and researching mechanical transition in water, are beneficial for their biological applications. Here, using polyelectrolyte complex fiber as a model system and reinforcing the fiber by stepwisely introducing additional coordination and covalent bonds, this investigated that the water effect on mechanical transition behaviors.
View Article and Find Full Text PDFJ Mater Chem B
December 2024
Supramolecular Chemistry Group, Centre of Macromolecular Chemistry (CMaC), Department of Organic and Macromolecular Chemistry, Ghent University, B-9000 Ghent, Belgium.
Dynamic polymer materials can be obtained by introducing supramolecular interactions between the polymer chains. Here we report on the preparation and mechanical properties of poly(methyl acrylate) (PMA) and poly(-butyl acrylate) (PBA) funcionalized with ureidopyrimidinone (UPy) in the side chains. In contrast to the traditional UPy with a methyl group, the selected UPy motif contained a branched alkyl side chain, which enhances solubility, compatibility with the polymer matrix and potentially prevents stacking of UPy dimers.
View Article and Find Full Text PDFSoft Matter
November 2024
Department of Chemical Engineering, University College London, London, UK.
This work investigates the design of stimuli-responsive Pickering emulsions (PEs) for transdermal drug delivery applications, by exploring the impact of stabilising microgels size and interactions on their rheological and release properties. Temperature-responsive poly(-isopropylacrylamide) microgels modified with 1-benzyl-3-vinylimidazolium bromide (pNIPAM--BVI) are synthesized in varying sizes and used to stabilise jojoba oil-in-water concentrated emulsions. The results reveals two distinct behaviours: for small microgels (∼300 nm), the PEs exhibit a smooth, uniform structure characterised by a mild yield stress, characteristic of soft glassy systems.
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