An acentric layer-pillared borate, LiBO·Hdap·HO (, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of BO and BO, has first been made under solvothermal conditions, in which the BO clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the BO clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by Hdap and Li cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KHPO).
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.inorgchem.1c02784 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
LiBO·Hdap·HO: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters.
Inorg Chem
November 2021
MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488, China.
An acentric layer-pillared borate, LiBO·Hdap·HO (, dap = 1,3-diaminopropane), cotemplated by organic and inorganic cations and build by mixed oxoboron cluster units of BO and BO, has first been made under solvothermal conditions, in which the BO clusters link each other to form 2D layers containing 9-membered ring (MR) windows, while the BO clusters join together to produce 1D chains that further perform as the pillars to connect neighboring layers, resulting in a 3D layer-pillared framework with 13- and 7-MR channels located by Hdap and Li cations, respectively. Its second harmonic generation shows a response of ∼2.1 times that of KDP (KHPO).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!