Optical robustness, uniformity, , , etc. dictate the applicability of nanocrystals. Based on a series of multimodal statistical analyses such as the Kolmogorov-Smirnov test, Lévy statistics, etc., we demonstrate that for CsPbBr perovskite nanocrystals (PNCs): (a) the extent of heterogeneity in the quality and associated physical processes is minimal; (b) the optical robustness is very high, and (c) indeed, a single PNC can depict optical behavior of its ensemble. In addition, toward prospective applications, an optically robust CsPbBr PNC exhibits (i) near- and (ii) minimal , which are extremely vital and complementary to its high defect tolerance.
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http://dx.doi.org/10.1021/acs.jpclett.1c02326 | DOI Listing |
Nat Commun
January 2025
Department of Chemistry and Biochemistry, The University of Oklahoma, Norman, OK, 73019, USA.
Surface defect-induced photoluminescence blinking and photodarkening are ubiquitous in lead halide perovskite quantum dots. Despite efforts to stabilize the surface by chemically engineering ligand binding moieties, blinking accompanied by photodegradation still poses barriers to implementing perovskite quantum dots in quantum emitters. To date, ligand tail engineering in the solid state has rarely been explored for perovskite quantum dots.
View Article and Find Full Text PDFNat Commun
January 2025
State Key Laboratory of Radiation Medicine and Protection, Collaborative Innovation Center of Radiological Medicine of Jiangsu Higher Education Institutions, and School for Radiological and Interdisciplinary Sciences (RAD-X), Soochow University, Suzhou, China.
High intrinsic detection efficiency is as decisive as high energy resolution. Scaling up detector volume has presented great challenges, preventing perovskite semiconductors from reaching sufficient detection efficiency. We report a hole-only virtual-Frisch-grid CsPbBr detector up to 2.
View Article and Find Full Text PDFDalton Trans
December 2024
College of Optoelectronic Engineering, Chongqing University of Post and Telecommunications, 400065, People's Republic of China.
With many fascinating characteristics, such as color-tunability, narrow-band emission, and low-cost solution processability, all-inorganic lead halide perovskite quantum dots (QDs) have attracted keen attention for electroluminescent light-emitting diodes (QLEDs) and display applications. However, the performance of perovskite QLED devices is intrinsically limited by the inefficient electrical carrier transport capacity. Herein, one facile but effective method is proposed to enhance the perovskite QLED performance by incorporating a short carbon chain ligand of 2-phenethylammonium bromide (PEABr) to passivate the CsPbBr QD surface.
View Article and Find Full Text PDFMikrochim Acta
December 2024
Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products/Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products, Guangxi Colleges Universities Key Laboratory of Optic-Electric Chemo/Biosensing and Molecular Recognition, Guangxi Minzu University, Nanning, 530006, China.
A dual supersaturation recrystallization method was employed to synthesize water-stable, highly sensitive cesium-lead halide perovskite nanocrystals (CsPbBr PNCs). The PNCs exhibited excellent water stability, a significant photoluminescence quantum efficiency of 83.03%, along with a narrow full width at half maximum (FWHM) of 20 nm.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Department of Materials Science and Engineering, City University of Hong Kong, Kowloon 999077, Hong Kong SAR, P. R. China.
The desorption of conventional ligands from the surface of halide perovskite nanocrystals (NCs) often causes their structural instability and deterioration of the optoelectronic properties. To address this challenge, we present an approach of using a bidentate Lewis base ligand, namely, 1,4-bis(diphenylphosphino)butane (DBPP), for the synthesis of CsPbBr NCs. The phosphine group of DBPP has a strong interaction with the PbBr precursor, forming a highly crystalline intermediate complex during the reaction.
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