The increased demand of energy due to the recent technological advances in diverse fields such as portable electronics and electric vehicles is often hindered by the poor capability of energy-storage systems. Although supercapacitors (SCs) exhibit higher power density than state-of-the art batteries, their insufficient energy density remains a major challenge. An emerging concept of hybrid supercapacitors (HSCs) with the combination of one capacitive and one battery electrode in a single cell holds a great promise to deliver high energy density without sacrificing power density and cycling stability. This Minireview elaborates the recent advances of use of nickel cobaltite (NiCo O ) as a potential positive electrode (battery-like) for HSCs. A brief introduction on the structural benefits and charge storage mechanisms of NiCo O was provided. It further shed a light on composites of NiCo O with different materials like carbon, polymers, metal oxides, and others, which altogether helps in increasing the electrochemical performance of HSCs. Finally, the key scientific challenges and perspectives on building high-performance HSCs for future-generation applications were reviewed.
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http://dx.doi.org/10.1002/cssc.202101465 | DOI Listing |
J Mater Chem B
December 2024
Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology (VIT), Vellore-632014, India.
Owing to the adverse consequences of excess glucose (Glu) and hydrogen peroxide (HO) on humans, it is imperative to develop an electrochemical sensor for detection of these analytes with good selectivity and sensitivity. Herein, a nanohybrid comprising nickel cobaltite nanoparticles (NiCoO NPs) embedded on conductive TiCT nanosheets (NSs) has been prudently designed and employed for the electrochemical detection of Glu and HO. The developed nanohybrid has been systematically characterized using morphological and spectral techniques, and then immobilized on a glassy carbon electrode (GCE).
View Article and Find Full Text PDFLuminescence
December 2024
Department of Pharmacology, Saveetha Dental College and Hospital, Saveetha Institute of Medical and Technical Sciences, Saveetha University, Chennai, India.
Sci Rep
November 2024
Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100, Torun, Poland.
Electrocatalytic water splitting for green hydrogen production necessitates effective electrocatalysts. Currently, commercial catalysts are primarily platinum-based. Therefore, finding catalysts with comparable catalytic activity but lower cost is essential.
View Article and Find Full Text PDFChemSusChem
September 2024
Department of Chemistry, Centre for Materials Science and Nanotechnology, University of Oslo, Gaustadalléen 21, NO-0349, Oslo, Norway.
Perovskite oxides have great flexibility in their elemental composition, which is accompanied by large adjustability in their electronic properties. Herein, we synthesized twelve perovskite oxide-based catalysts for the oxygen evolution reaction (OER) in alkaline media. The catalysts are based on the parent oxide perovskite BaGdLaCoO (BGLC587) and are synthesized through the sol-gel citrate synthesis route.
View Article and Find Full Text PDFHeliyon
August 2024
Department of Physics, Aligarh Muslim University, Aligarh, 202002, India.
Zinc Cobaltite (ZCO) and Nickel Oxide (NiO) nanoparticles (NPs) were synthesized using a sol-gel technique, and their composites with different weight ratios were prepared using a straightforward sonication method. The NiO and ZCO NPs had small crystallite size of 10 nm and 18 nm, respectively. According to the ultraviolet-visible (UV-Vis) spectra, pure NiO and ZCO NPs exhibited band gaps of ∼3.
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