We report herein new luminescent rhenium(I) perfluorobiphenyl complexes that reacted specifically with the cysteine residue of the π-clamp sequence (FCPF) to afford novel peptide-based imaging reagents, photosensitisers for singlet oxygen and enzyme sensors.
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Nikolaev Institute of Inorganic Chemistry, SB RAS, 3, Lavrentiev Ave., 630090, Novosibirsk, Russia.
Chiral rhenium(I) emitters exhibiting circularly polarized phosphorescence (CPP) are an attractive mainstay for CP organic light-emitting diodes (CP-OLEDs). However, the efficiency of such emitters is not ideal, and they have never been explored for circularly polarized electroluminescence (CPEL) applications. Here, we have tailored robust chiral Re(I) complexes with improved CPP properties, and demonstrated CPEL from rhenium emitters for the first time.
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Université de Strasbourg, CNRS Institut de Physique et Chimie des Matériaux de Strasbourg, UMR 7504 23 rue du Loess, 67034 Strasbourg, France.
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