Colors enable interaction and communication between living species in a myriad of biological and artificial environments. While living organisms feature low-power mechanisms to dynamically control color in soft tissues, man-made color-changing devices remain predominantly rigid and energy intensive. Here, architectured composites that display striking color changes when stretched in selective directions under ambient light with minimum power input are reported. The orientation-dependent color change results from the rotation of reflective coated platelets that are embedded in a soft polymer matrix and pre-aligned in a well-defined architecture. The light reflected by the platelets generates structural color defined by the oxide coating on the platelet surface. By magnetically programming the initial orientation and spatial distribution of selected platelets within the soft matrix, composites with strain-modulated color-changing effects that cannot be achieved using state-of-the-art technologies are created. The proposed concept of strain-induced architectured color can be harnessed to develop low-power smart stretchable displays, tactile synthetic skins, and autonomous soft robotic devices that undergo fast and reversible color changes through the mechano-optic coupling programmed within their soft composite architecture.
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http://dx.doi.org/10.1002/adma.202104874 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Key Laboratory of Biobased Polymer Materials, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China.
Acta Biomater
October 2024
Department of Neurobiology, Physiology, & Behavior, University of California Davis, United States; Department of Physical Medicine and Rehabilitation, University of California Davis, United States. Electronic address:
Collagen fiber architecture within the skeletal muscle extracellular matrix (ECM) is significant to passive muscle mechanics. While it is thought that collagen fibers re-orient themselves in response to changes in muscle length, this has not been dynamically visualized and quantified within a muscle. The goal of this study was to measure changes in collagen alignment across a range of muscle lengths and compare the corresponding alignment to muscle mechanics.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Institute of Nanotechnology, Karlsruhe Institute of Technology, Kaiserstrasse 12, 76131, Karlsruhe, Germany.
Group 14/16 adamantane-type hybrid clusters of the type [(RT)E] (T=group 14 element, E=group 16 element, R=organic group) have been reported to emit white-light when irradiated in an amorphous state with a continuous-wave (CW) infrared laser diode. This effect is enhanced if the cluster core is varied from a binary to a more complex composition. To further explore this phenomenon, we synthesized clusters with a multinary R/R'-T/T'-E/E' composition, including isolobal replacement of E with CH, in [(2-NpSi){CHSn(S)Ph}] (1, Np=naphthyl).
View Article and Find Full Text PDFNano Lett
September 2024
Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, 110016 Shenyang, People's Republic of China.
We present a novel approach to induce charge density waves (CDWs) in metallic MAZ materials, resembling the behavior observed in transition metal dichalcogenides (TMDCs). This method leverages the intercalating architecture to maintain the same crystal field and Fermi surface topologies. Our investigation reveals that CDW instability in these materials arises from electron-phonon coupling (EPC) between the band and longitudinal acoustic (LA) phonons, mirroring TMDC's behavior.
View Article and Find Full Text PDFJ Am Chem Soc
June 2024
College of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China.
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