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Upconversion nanoparticles/carbon dots (UCNPs@CDs) composite for simultaneous detection and speciation of divalent and trivalent iron ions. | LitMetric

Upconversion nanoparticles/carbon dots (UCNPs@CDs) composite for simultaneous detection and speciation of divalent and trivalent iron ions.

Anal Chim Acta

Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, Qingdao, 266071, China. Electronic address:

Published: October 2021

AI Article Synopsis

  • This study explores the use of carbon dots modified NaYF:Yb, Er nanoparticles as a fluorescent nanoprobe for detecting iron (Fe) concentrations.
  • It successfully quantifies Fe levels ranging from 5-80 μmol L through fluorescence quenching at specific wavelengths when excited by light.
  • The created nanoprobe exhibits strong anti-interference, good fluorescence stability, and effectiveness in analyzing real samples, making it a promising tool for simultaneous Fe detection.

Article Abstract

In this study, the application of carbon dots (CDs) modified NaYF:Yb, Er nanoparticles (UCNPs@CDs) as the fluorescent nanoprobe for simultaneous detection of Fe and Fe was investigated. Fe quantification (5-80 μmol L) was achieved, as a result of Fe induced fluorescence quenching of UCNPs@CDs at 434 nm (under the 336 nm excitation). The chelate (Fe-phen) formed by Fe and 1,10-phenanthroline had a broad absorption centered at 510 nm, due to inner filter effect (IFE), Fe quantification (4-120 μmol L) was achieved as a result of (Fe-phen) induced fluorescence quenching of UCNPs@CDs at 545 nm (under the 980 nm excitation). The resultant UCNPs@CDs probe, with excellent anti-interference capability, favorable fluorescence stability, and convincing performance in real sample analysis, showed promising application in simultaneous detection of Fe and Fe.

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Source
http://dx.doi.org/10.1016/j.aca.2021.338973DOI Listing

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