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The metal-organic framework (MOF)-based polyamide (PA) membranes applied for desalination with high permeability and selectivity are attracting more and more attention. However, the design and fabrication of high-quality and stable MOF-based PA nanocomposite reverse osmosis (RO) membrane still remain a big challenge. Herein, Fe-polyphenolic complex coating via interfacial coordination was first explored as an interlayer of an in situ assembled stable and high-quality Fe(BTC)-based PA nanocomposite RO membranes for desalination. Although depositing the Fe-polyphenolic complex on the polymer support, sufficient heterogeneous nucleation sites for the in situ synthesizing Fe(BTC) are provided. Using this strategy, we can not only facilely prepare continuous MOF-based PA nanocomposite RO membranes, ignoring the complicated and time-consuming co-blending process and the MOF-particle aggregation, but also restrict the formation of PA matrix inside the pores of the support membrane and increase the rigidity of the polyamide chain. The method also gives a proper level of generality for the fabrication of versatile stable MOF-based PA RO membranes on various supports. The prepared PA/Fe(BTC) composite membrane exhibited excellent separation performance with a large permeate flux of 2.93 L m h bar and a high NaCl rejection of 96.8%.
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http://dx.doi.org/10.1021/acsami.1c13801 | DOI Listing |
J Econ Entomol
December 2024
Key Laboratory of Plant Protection Resources and Pest Management of Ministry of Education, College of Plant Protection, Northwest A&F University, Yangling, China.
Arbuscular mycorrhizal fungi may promote growth and stress resilience of plants, particularly under water-deficit conditions. However, interactions among mycorrhizal fungi, wheat plants, and aphids like the English grain aphid Sitobion avenae (Hemiptera: Aphididae) under water-deficit stress are still not well understood. Here, we examined the colonization of the fungus Claroideoglomus etunicatum (Glomerales: Claroideoglomeraceae) on wheat, and its effects on development and behavior of S.
View Article and Find Full Text PDFMol Genet Genomics
December 2024
ENT Institute and Department of Otorhinolaryngology, Eye & ENT Hospital, Fudan University, 83 Fen Yang Road, Shanghai, 200031, China.
Low-frequency non-syndromic hearing loss (LFNSHL) is a rare auditory disorder affecting frequencies ≤ 2000 Hz. To elucidate its genetic basis, we conducted whole-exome sequencing on nine Chinese families (31 affected individuals) with LFNSHL. Four heterozygous pathogenic variants, including two novel variants, were identified in common LFNSHL-related genes (WFS1, DIAPH1) and less common genes (TNC, EYA4), achieving a 44% genetic diagnosis rate.
View Article and Find Full Text PDFClin Exp Med
December 2024
Department of Virology, National Institute of Public Health NIH-National Research Institute, Warsaw, Poland.
Decades of basic and translational research have led to a momentum shift in dissecting the relationship between immune cells and cancer. This culminated in the emergence of breakthrough immunotherapies that paved the way for oncologists to manage certain hard-to-treat cancers. The application of high-throughput techniques of genomics, transcriptomics, and proteomics was conclusive in making and expediting the manufacturing process of cancer vaccines.
View Article and Find Full Text PDFKnee Surg Sports Traumatol Arthrosc
December 2024
Center of Orthopaedics and Traumatology, Brandenburg Medical School, University Hospital Brandenburg/Havel, Brandenburg an der Havel, Germany.
The evolution of orthopaedics has witnessed a pronounced shift from generalist practice to subspecialisation, a trend that has fundamentally reshaped the field over the past century. Originally, orthopaedic surgeons were trained to address a broad spectrum of musculoskeletal conditions. However, increasing complexity and specialization in knowledge have driven a progressive narrowing of focus within orthopaedics.
View Article and Find Full Text PDFJ Med Chem
December 2024
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, Sun Yat-Sen University, Guangzhou 510006, P. R. China.
ER-phagy is a double-edged sword in the occurrence, development, and treatment of cancer; especially, its functions in immunotherapy are still unknown. In this work, we designed a theranostic Re complex () containing a BODIPY-derived ligand and a β-carboline ligand to target the endoplasmic reticulum (ER) and block ER-phagy at the late stages. Interestingly, as validated both in vitro and in vivo, ER-phagy blockage greatly enhances the capability of to induce immunogenic cell death (ICD).
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!