The first interdigitated MX-type chain complex with infinite π-stacked arrays was synthesized. The synchronization between a Pt-Br⋯ chain and π-stacking periodicities led to the longest M-X-M distance (6.6978(15) Å) and nil or negligible intervalence charge transfer, which is essential to realize the Robin-Day class I mixed valence state in MX chains.
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| http://dx.doi.org/10.1039/d1dt02996g | DOI Listing |
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