The effective engineering of light absorption has been the focus of intensive research to realize the novel optoelectronic devices based on a topological insulator, a unique topologically protected surface Dirac-state quantum material with excellent prospects in electronics and photonics. Here, we theoretically proposed a versatile platform for manipulating the light-matter interaction employing the dynamically tunable coherent perfect absorption (CPA) in the topological insulator BiSbTeSe(BSTS). By simply varying the phase difference between two coherent counter-propagating beams, the BSTS-based CPA device can be continuously switched from the high transparency state to the strong absorption state, leading to the modulation of absorption ranging from 0.2% to 99.998%. Under the illumination of TE-polarized wave, the high absorption (>90%) can be implemented within a broad range from 0.47 to 1.51 μm through a proper incident angle alteration. In addition, the quasi-CPA wavelength can be flexibly selected by tuning the bulk thickness of BSTS film while maintaining high modulation depth of 10. Such BSTS-based CPA device with flexible tunability, wide absorption modulation range, and high modulation depth is expected to be utilized in a wide range of potential applications such as in next-generation coherent detectors, coherent modulators, all-optical switches, and signal processors.
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http://dx.doi.org/10.1364/OE.435440 | DOI Listing |
ACS Photonics
January 2025
Foundation of Research and Technology Hellas, Institute of Electronic Structure and Laser, Heraklion 71110, Greece.
We demonstrate a simple, low-cost, and ultracompact chiral resonant metasurface design, which, by strong local coupling to a quantum gain medium (quantum emitters), allows to implement an ultrathin metasurface laser, capable of generating tunable circularly polarized coherent lasing output. According to our detailed numerical investigations, the lasing emission can be transformed from linear to circular and switch from right- to left-handed circularly polarized (CP) not only by altering the metasurface chiral response but also by changing the polarization of a linearly polarized pump wave, thus enabling dynamic lasing-polarization control. Given the increasing interest for CP laser emission, our chiral metasurface laser design proves to be a versatile yet straightforward strategy to generate a strong and tailored CP emission laser, promising great potential for future applications in both photonics and materials science.
View Article and Find Full Text PDFNatl Sci Rev
February 2025
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China.
Organic red/near-infrared (NIR) room-temperature phosphorescence (RTP) holds significant potential for autofluorescence-free bioimaging and biosensing due to its prolonged persistent luminescence and exceptional penetrability. However, achieving activatable red/NIR organic RTP probes with tunable emission in aqueous solution remains a formidable challenge. Here we report on aqueous organic RTP probes with red/NIR phosphorescence intensity and lifetime amplification.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Huzhou Key Laboratory of Materials for Energy Conversion and Storage, College of Science, Huzhou University, Huzhou 313000, China. Electronic address:
1550 nm-responsive upconversion luminescence (UCL) has attracted increasing attention due to its potential applicability in a new generation of bio-probes and photonic devices. However, regulating multi-color UCL with pump power remains a challenge. In this work, through constructing the coupling between Er and Tm ions and suppressing the energy transfer upconversion process of Er ions, the response of UCL color in Gd(MoO):Er/Tm to pump power is enhanced significantly.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117585, Singapore.
Nanomaterials that engage in well-defined and tunable interactions with proteins are pivotal for the development of advanced applications. Achieving a precise molecular-level understanding of nano-bio interactions is essential for establishing these interactions. However, such an understanding remains challenging and elusive.
View Article and Find Full Text PDFJ Chem Eng Data
January 2025
Department of Chemical and Geological Sciences, University of Cagliari, 09042 Monserrato, Italy.
Deep eutectic solvents (DESs) have recently gained attention due to their tailorable properties and versatile applications in several fields, including green chemistry, pharmaceuticals, and energy storage. Their tunable properties can be enhanced by mixing DESs with cosolvents such as ethanol, acetonitrile, and water. DESs are structurally complex, and molecular modeling techniques, including quantum mechanical calculations and molecular dynamics simulations, play a crucial role in understanding their intricate behavior when mixed with cosolvents.
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