Metamaterials of metal-insulator-metal structures represent effective ways in manipulating light absorbance for photodetection, sensing, and energy harvesting etc. Most of the time, specular reflection has been used in characterizing resonances of metamaterials without considering diffuse scattering from their periodic subwavelength units. In this paper, we investigate diffuse reflection in metasurfaces made of periodic metallic disks in the mid-infrared region. Integrating sphere-based spectral measurements indicate that diffuse reflection is dominated by grating diffractions, which cause diffuse scattering in a spectral region with wavelengths less than that of the first order Rayleigh anomaly. The diffuse reflection is greatly enhanced by the metasurface resonance and exhibits a general increase towards shorter wavelengths, which not only causes a significant difference in evaluating the metamaterial resonant absorption efficiency but also a small blue-shift of the resonance frequency. These findings are helpful for designing and analyzing metamaterial resonant properties when diffuse scattering is taken into account.
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http://dx.doi.org/10.1364/OE.433833 | DOI Listing |
Commun Chem
January 2025
Faculty of Engineering, Hokkaido University, Kita 13, Nishi 8, Kita-ku, Sapporo, Hokkaido, 060-8628, Japan.
Photoinduced metal-to-ligand (or ligand-to-metal) charge-transfer (CT) states in metal complexes have been extensively studied toward the development of luminescent materials. However, previous studies have mainly focused on CT transitions between d- and π-orbitals. Herein, we report the demonstration of CT emission from 4f- to π-orbitals using a trivalent europium (Eu(III)) complex, supported by both experimental and theoretical analyses.
View Article and Find Full Text PDFSci Rep
January 2025
Laboratory of Materials, Nanotechnologies and Environment, Center of Sciences of Materials, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Battouta, BP:1014, 10000, Rabat, Morocco.
In this study, novel polyaniline-coated perovskite nanocomposites (PANI@CoTiO and PANI@NiTiO) were synthesized using an in situ oxidative polymerization method and evaluated for the photocatalytic degradation of Rhodamine B (RhB) a persistent organic pollutant. The nanocomposites displayed significantly enhanced photocatalytic efficiency compared to pure perovskites. The 1%wt PANI@NiTiO achieved an impressive 94% degradation of RhB under visible light after 180 min, while 1wt.
View Article and Find Full Text PDFAcc Chem Res
January 2025
The Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford OX1 3QR, U.K.
ConspectusThe discovery of reversible hydrogenation using metal-free phosphoborate species in 2006 marked the official advent of frustrated Lewis pair (FLP) chemistry. This breakthrough revolutionized homogeneous catalysis approaches and paved the way for innovative catalytic strategies. The unique reactivity of FLPs is attributed to the Lewis base (LB) and Lewis acid (LA) sites either in spatial separation or in equilibrium, which actively react with molecules.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Rutgers University - Newark, Newark, NJ 07102, USA.
In this study, we present the growth of large (millimeter- and centimeter-scale) crystals of RbSnBr double perovskite a hydrothermal process. The crystals and powders were successfully synthesized, yielding light-yellow products, and subjected to comprehensive characterization using powder and single crystal X-ray diffraction (XRD), energy-dispersive spectroscopy (EDS) point analysis, and UV-Vis diffuse reflectance spectroscopy. Previously, methods such as solution growth, evaporation, and gel techniques have been employed to synthesize RbSnBr.
View Article and Find Full Text PDFJ Neuroradiol
January 2025
Department of Neurosurgery, University of Occupational and Environmental Health, Kitakyushu, Japan.
Introduction: Our previous work demonstrated that evaluating large ischemic cores using the apparent diffusion coefficient (ADC) could predict EVT outcomes, with the most frequent ADC (peak ADC) ≥520×10 mm/s associated with better clinical results. Since the degree of ADC reduction reflects the severity of ischemic stress, this study aimed to assess the utility of an ADC color map in visualizing this stress.
Patients And Methods: This retrospective cohort study included consecutive patients with a low Alberta Stroke Program Early Computed Tomography Score (ASPECTS) using diffusion-weighted imaging (DWI) who underwent successful EVT recanalization between April 2014 and March 2023.
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