Taking the influence of alloying elements into consideration, a hardness prediction model based on a newly proposed parameter named actual carbon diffusion time (ACDT), which was calculated by combining temperature history with carbon diffusivity, is developed in this paper. The hardness distribution was directly derived from a 3D thermal model, which was constructed to simulate the laser surface hardening of AISI 1045, and from which the temperature history was also obtained. Using this 3D thermal model, the geometric characteristics after laser hardening (e.g., the width of the hardened layer, the depth of the phase change layer) were determined according to the martensitic transformation. The influences of the scanning speed and the laser power on the geometric characteristics were investigated, and the relations among the geometric characteristics after laser hardening were further determined. The laser hardening experiments with various parameters were conducted, and it was found that the hardness can be accurately predicted using the developed hardness prediction model (R-squared, 97.0%). The proposed parameter ACDT, as the core of the hardness prediction model in this paper, broadens the way for hardness prediction in laser hardening with the alloying effect involved.
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http://dx.doi.org/10.1364/AO.432225 | DOI Listing |
Sci Rep
January 2025
Department of Mechanical Engineering, Indian Institute of Technology Guwahati, Guwahati, 781039, India.
Refractory High-Entropy Alloys (RHEAs), such as NbMoTaW, MoNbTaVW, HfNbTaZr, ReHfNbTaW, NbTiAlVTaHfW, TiNbMoTaW (x = 0, 0.25, 0.5, 0.
View Article and Find Full Text PDFInorg Chem
January 2025
Institute of Materials Research and Engineering (IMRE), Agency for Science, Technology and Research (A*STAR), 2 Fusionopolis Way, Innovis #08-03, Singapore 138634, Republic of Singapore.
High-entropy ceramics hold promise for application as thermal barrier coating materials. However, a key challenge in practical applications lies in the low fracture toughness compared to that of yttria-stabilized zirconia (YSZ). Herein, we designed (Hf,Zr,Ce,)O-AlO (M = Y, Ca, and Gd) ceramic composites by following a set of fundamental guidelines.
View Article and Find Full Text PDFJ Food Sci
January 2025
Amasya Social Sciences Vocational School, Amasya University, Amasya, Turkey.
In this study, quinoa, which is a good alternative for celiacs, was tried to be used instead of flour by sprouting it and drying it in the airfryer. Flour obtained from quinoa seeds prevents spreading and hardens the product. It was predicted that this problem could be overcome by germination and drying in the airfryer.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
MOE Key Laboratory for Non-equilibrium Synthesis and Modulation of Condensed Matter, Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics, School of Physics, Xi'an Jiaotong University, 710049, Xi'an, Shaanxi, P. R. China.
Exploration of new superconducting or superhard transition-metal borides has attracted extensive interest in the past few decades. In this study, we conducted comprehensive theoretical investigations in the scandium-boron binary system by employing a structural search method based upon first-principles density functional theory. Among the six predicted superconducting scandium-borides, ScB (3̄) has the highest superconducting transition temperature = 12.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Laboratoire de Chimie Hétérocyclique, Produits Naturels et Réactivité (LR11SE39), Faculté des Sciences de Monastir, Université de Monastir, Avenue de l'Environnement, Monastir 5019, Tunisie.
The kinetics of the σ-complexation reactions of 3,5-dicyanothiophene with a series of cyclic secondary amines - has been studied in water and acetonitrile at 20 °C. Through the linear free energy relationship (LFER) log = s ( + ), the electrophilicity parameter of 3,5-dicyanothiophene has been determined and then integrated into the electrophilicity scale established by Mayr. Molecular dynamics (MD) simulations have been employed to elucidate the reversal in reactivity order between piperidine and pyrrolidine observed in water.
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