AI Article Synopsis
- Mn cage complexes are uncommon, and those isolated in solid form aren't stable in water or organic solvents.
- This study introduces the first known mononuclear Mn clathrochelates, which contain manganese in the +4 oxidation state.
- These complexes demonstrate high stability both as crystals and in solutions, along with diverse redox reactions.
Article Abstract
Mn cage complexes are rare, and the ones successfully isolated in the solid state are not stable in water and organic solvents. Herein, we present the first report of mononuclear Mn clathrochelates, in which the encapsulated metal exists in the oxidation state +4. The complexes are extremely stable in the crystalline state and in solutions and show rich redox chemistry.
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| http://dx.doi.org/10.1039/d1cc04870h | DOI Listing |
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