Microplastic (MP) contamination has been reported to be higher in terrestrial compared to aquatic environments. This is probably due to the fact that plastic items are mostly produced and used in terrestrial environments and have a longer residence time. However, there are several links between the terrestrial and aquatic environments. We analyzed drainage water samples from agricultural soils in the Seeland, a heavily drained agriculturally intensive area in Switzerland for its MP (>100 μm) concentration and composition. We found MP in relevant numbers (mean 10.5 ± 9.5 N L). The polymers were mainly PA and PE, and the size distribution showed an exponential increase with decreasing particle size. The results show considerable MP concentrations in drainage water and imply a transport of MP in soils down to the drainage pipes. Given the large areas drained both in Switzerland and globally, it is proposed that MP leaching from soil can be a significant source of MP to aquatic ecosystems. Such a contribution should be considered when dealing with MP cycling on a local to global scale.
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http://dx.doi.org/10.1016/j.scitotenv.2021.150709 | DOI Listing |
Adv Mater
December 2024
Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, School of Chemistry, Xi'an Jiaotong University, Xi'an, 710049, China.
Hydrogel bioadhesives with adequate wet adhesion and swelling resistance are urgently needed in clinic. However, the presence of blood or body fluid usually weakens the interfacial bonding strength, and even leads to adhesion failure. Herein, profiting from the unique coupling structure of carboxylic and phenyl groups in one component (N-acryloyl phenylalanine) for interfacial drainage and matrix toughening as well as various electrostatic interactions mediated by zwitterions, a novel hydrogel adhesive (PAAS) is developed with superior tissue adhesion properties and matrix swelling resistance in challenging wet conditions (adhesion strength of 85 kPa, interfacial toughness of 450 J m, burst pressure of 514 mmHg, and swelling ratio of <4%).
View Article and Find Full Text PDFBiogeochemistry
December 2024
Department of Natural Resources and the Environment, University of New Hampshire, 56 College Road, Durham, NH USA.
Unlabelled: Climate and atmospheric deposition interact with watershed properties to drive dissolved organic carbon (DOC) concentrations in lakes. Because drivers of DOC concentration are inter-related and interact, it is challenging to assign a single dominant driver to changes in lake DOC concentration across spatiotemporal scales. Leveraging forty years of data across sixteen lakes, we used structural equation modeling to show that the impact of climate, as moderated by watershed characteristics, has become more dominant in recent decades, superseding the influence of sulfate deposition that was observed in the 1980s.
View Article and Find Full Text PDFBiomaterials
December 2024
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai, 201620, China.
Moisture induced by wound exudate is crucial throughout the wound repair process. The dressing directly affects the absorption, permeation, and evaporation of the wound exudate. However, most dressings in clinical often result in excessive dryness or moisture of wound due to their monotonous structure and function, leading to ineffective thermodynamic control of evaporation enthalpy.
View Article and Find Full Text PDFMar Pollut Bull
December 2024
Department of Chemical, Environmental, and Materials Engineering, University of Miami, Coral Gables, FL 33146. Electronic address:
Correlation and cluster analysis protocols for analyzing multiple-parameter water-quality data sets are presented and demonstrated. A novel cluster analysis methodology is developed that identifies parameters that are either directly or indirectly correlated. Application of these analyses was demonstrated using multi-parameter water-quality measurements in Biscayne Bay and the primary drainage canals in South Florida.
View Article and Find Full Text PDFMar Pollut Bull
December 2024
Aix Marseille University, Université de Toulon, CNRS, IRD, MIO UM110, 13288 Marseille, France; Department Water-Environment-Oceanography, University of Science and Technology of Hanoi (USTH), Vietnamese Academy of Science and Technology (VAST), 18 Hoang Quoc Viet, Hanoi 100000, Viet Nam; IRD, Chulalongkorn University, 254 Henri Dunant Road, Pathumwan, 10330 Bangkok, Thailand.
Halong Bay (northern Vietnam) is heavily affected by human activities. Metals and metalloids (e.g.
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