Novel modes of synchronization in star networks of coupled chemical oscillators.

Photochemically coupled micro-oscillators are studied experimentally and computationally in star networks to investigate the modes and mechanisms of synchronization. The micro-oscillators are catalyst-loaded beads that are placed in catalyst-free Belousov-Zhabotinsky (BZ) solutions. The properties of the photochemical coupling between the oscillators are determined by the composition of the BZ reaction mixtures, and both excitatory coupling and inhibitory coupling are studied. Synchronization of peripheral oscillators coupled through a hub oscillator is exhibited at coupling strengths leading to novel modes of synchronization of the hub with the peripheral oscillators. A theoretical analysis provides insights into the mechanism of the synchronization. The heterogeneous peripheral oscillators have different phase velocities that give rise to a phase divergence; however, the perturbation from the hub acts to realign the phases by delaying the faster oscillators more than the slower oscillators.