Functional nanocoatings of hollow-core microstructured optical fibers (HC-MOFs) have extended the domain of their applications to biosensing and photochemistry. However, novel modalities typically come with increased optical losses since a significant surface roughness of functional layers gives rise to additional light scattering, restricting the performance of functionalization. Here, the technique that enables a biocompatible and removable nanocoating of HC-MOFs with low surface roughness is presented. The initial functional film is formed by a layer-by-layer assembly of bovine serum albumin (BSA) and tannic acid (TA). The alkaline etching at pH 9 results in the reduction of surface roughness from 26 nm to 3 nm and decreases fiber optical losses by three times. The nanocoating can be fully removed within 7 min of the treatment. Natural biocompatibility of BSA alongside antibacterial and antifouling properties of TA makes the presented nanocoating promising for biophotonic applications.
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http://dx.doi.org/10.1364/OL.436220 | DOI Listing |
Chem Rev
January 2025
Department of Chemical & Biomolecular Engineering, University of California, Irvine, California 92697, United States.
The reactions critical for the energy transition center on the chemistry of hydrogen, oxygen, carbon, and the heterogeneous catalyst surfaces that make up electrochemical energy conversion systems. Together, the surface-adsorbate interactions constitute the electrochemical interphase and define reaction kinetics of many clean energy technologies. Practical devices introduce high levels of complexity where surface roughness, structure, composition, and morphology combine with electrolyte, pH, diffusion, and system level limitations to challenge our ability to deconvolute underlying phenomena.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Materials, ETH Zurich, 8093 Zurich, Switzerland.
Colloidal gels, ubiquitous in industrial applications, can undergo reversible solid-to-liquid transitions. Recent work demonstrates that adding surface roughness to primary particles enhances the toughness and influences the self-healing properties of colloidal gels. In the present work, we first use colloidal probe atomic force microscopy (CP-AFM) to assess the quantitative changes in adhesive and frictional forces between thermoresponsive particles as a function of their roughness.
View Article and Find Full Text PDFJ Contemp Dent Pract
October 2024
Department of Prosthodontics, Government Dental College, Kozhikode, Kerala, India, Orcid: https://orcid.org/0000-0003-1456-3851.
Aim: The aim of this study was to compare the surface roughness and color stability of polyetheretherketone (PEEK) with those of conventional interim prosthetic materials like polymethylmethacrylate, bis-acrylic composite, and rubberized diurethane dimethacrylate, following immersion in solutions of varying pH value.
Materials And Methods: A total of 320 circular discs with 10 mm diameter and 2 mm height were divided based on the fabrication ( = 80)-group A: polymethylmethacrylate; group B: bis-acrylic composite; group R: rubberized diurethane; and group P: hot-pressed PEEK-and were subjected to baseline measurement of roughness ( = 40) and color ( = 40) using 3D profilometer and UV-Vis spectrophotometer, respectively. Later, 10 samples from each group were immersed in distilled water, black coffee, green tea, and Pepsi, respectively, for 120 days, and measurements of roughness and color were repeated.
J Dent Sci
January 2025
School of Dental Technology, College of Oral Medicine, Taipei Medical University, Taipei, Taiwan.
Background/purpose: Early osseointegration of titanium (Ti) dental implants relies on the surface topography. Surface modification of Ti seeks to enhance bone regeneration around implants. Acid etching is the simple, less technique sensitive and cost-effective technique for surface treatment.
View Article and Find Full Text PDFJ Dent Sci
January 2025
School of Dentistry, College of Oral Medicine, Taipei Medical University, Taipei, Taiwan.
Background/purpose: Osseointegration potential is greatly depended on the interaction between bone cells and dental implant surface. Since zirconia ceramic has a bioinert surface, functionalization of the surface with an organic compound allylamine was conducted to overcome its drawback of minimal interaction with the surrounding bone.
Materials And Methods: The zirconia surface was initially treated with argon glow discharge plasma (GDP), then combined with amine plasma at three different conditions of 50-W, 75-W and 85-W, to prepare the final samples.
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