Hierarchical MoC@CNT Hybrid Structure Formation for the Improved Lithium-Ion Battery Storage Performance.

2-D transition metal carbides (TMCs)-based anode materials offer competitive performance in lithium-ion batteries (LIBs) owing to its excellent conductivity; cheaper, flexible uses; and superior mechanical stability. However, the electrochemical energy storage of TMCs is still the major obstacle due to their modest capacity and the trends of restacking/aggregation. In this report, the MoC nanosheets were attached on conductive CNT network to form a hierarchical 2D hybrid structure, which not only alleviated the aggregation of the MoC nanoparticle and facilitated the rapid transference of ion/electron, but also adapted effectually to the hefty volume expansion of MoC nanosheets and prevented restacking/collapse of MoC structure. Benefitting from the layered Mo@CNT hybrid structure, the charge/discharge profile produced a 200 mAh g discharge-specific capacity (second cycle) and 132 mAh g reversible-discharge discharge-specific capacity (after 100 cycles) at 50 mA g current density, with high-speed competency and superior cycle stability. The improved storage kinetics for Mo@CNT hybrid structure are credited to the creation of numerous active catalytic facets and association reaction between the CNT and MoC, promoting the efficient electron transfer and enhancing the cycling stability.