Toluene is one of the pollutants that are dangerous to the environment and human health and has been sorted into priority pollutants; hence, the control of its emission is necessary. Due to severe problems caused by toluene, different techniques for the abatement of toluene have been developed. Catalytic oxidation is one of the promising methods and effective technologies for toluene degradation as it oxidizes it to CO and does not deliver other pollutants to the environment. This paper highlights the recent progressive advancement of the catalysts for toluene oxidation. Five categories of catalysts, including noble metal catalysts, transition metal catalysts, perovskite catalysts, metal-organic frameworks (MOFs)-based catalysts, and spinel catalysts reported in the past half a decade (2015-2020), are reviewed. Various factors that influence their catalytic activities, such as morphology and structure, preparation methods, specific surface area, relative humidity, and coke formation, are discussed. Furthermore, the reaction mechanisms and kinetics for catalytic oxidation of toluene are also discussed.
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http://dx.doi.org/10.1007/s11356-021-16492-9 | DOI Listing |
Front Biosci (Landmark Ed)
December 2024
Research Centre for Medical Genetics, 115522 Moscow, Russia.
Background: There is a growing interest in exploring the biological characteristics of nanoparticles and exploring their potential applications. However, there is still a lack of research into the potential genotoxicity of fullerene derivatives and their impact on gene expression in human cells. In this study, we investigated the effects of a water-soluble fullerene derivative, C60[C6H4SCH2COOK]5H (F1), on human embryonic lung fibroblasts (HELF).
View Article and Find Full Text PDFJACS Au
December 2024
Department of Chemistry, University of Connecticut, Storrs, Connecticut 06269-3060, United States.
Red-light absorbing photoredox catalysts offer potential advantages for large-scale reactions, expanding the range of usable substrates and facilitating bio-orthogonal applications. While many red-light absorbing/emitting fluorophores have been developed recently, functional red-light absorbing photoredox catalysts are scarce. Many photoredox catalysts rely on long-lived triplet excited states (triplets), which can efficiently engage in single electron transfer (SET) reactions with substrates.
View Article and Find Full Text PDFACS Appl Nano Mater
January 2024
Department of Chemistry, University of Central Florida, Orlando, Florida 32816 (USA).
Understanding the origin of enhanced catalytic activity is critical to heterogeneous catalyst design. This is especially important for non-noble metal-based catalysts, notably metal oxides, which have recently emerged as viable alternatives for numerous thermal catalytic processes. For thermal catalytic reduction/hydrogenation using metal oxide nanoparticles, enhanced catalytic performance is typically attributed to increased surface area and oxygen vacancies.
View Article and Find Full Text PDFACS Cent Sci
December 2024
Department of Chemistry, Shanghai Stomatological Hospital & School of Stomatology, State Key Laboratory of Molecular Engineering of Polymers, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China.
An efficient regiospecific co-assembly (RSCA) strategy is developed for general synthesis of mesoporous metal oxides with pore walls precisely decorated by highly dispersed noble metal nanocrystals with customized parameters (diameter and composition). It features the rational utilization of the specific interactions between hydrophilic molecular precursors, hydrophobic noble metal nanocrystals, and amphiphilic block copolymers, to achieve regiospecific co-assembly as confirmed by molecular dynamics simulations. Through this RSCA strategy, we achieved a controllable synthesis of a variety of functional mesoporous metal oxide composites (e.
View Article and Find Full Text PDFACS Cent Sci
December 2024
Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Centre of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China.
Electrochemical conversion of CO to hydrocarbons is a promising approach to carbon neutrality and energy storage. The formation of reaction intermediates involves crucial steps of proton transfer, making it essential to understand the role of protons in the electrochemical process to control the product selectivity and elucidate the underlying catalytic reaction mechanism of the CO electrochemical reduction (CORR). In this work, we proposed a strategy to regulate product selectivities by tuning local proton transport rates through a surface resin layer over cuprous oxides.
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