AI Article Synopsis
- A high-precision calorimeter was utilized to obtain thermodynamic data on substituted triazines, focusing on their combustion properties.
- The study reported the first enthalpy of combustion and formation values for six specific substituted triazines, establishing a new data set for these compounds.
- The enthalpy values derived ranged from -478.60 to -1109.80 kJ/mol at 25 °C, highlighting significant variations among the different triazines tested.
Article Abstract
To obtain reliable thermodynamic data on substituted triazines, it is necessary to use a calorimeter that is capable of high precision with small quantities of sample and in which a homogeneous solution of the corrosive combustion products can be maintained. The enthalpies of combustion of six substituted triazines have been determined in a platinum-lined adiabatic rotating bomb calorimeter. These are the first determinations of enthalpies of combustion or formation to have been reported for these compounds. The values derived for the enthalpies of formation in kJ/mol at 25 °C are as Follows: 2,4,6-trimethoxy-l,3,5-triazine, - 478.60± 0.87; 2,4,6-triethozy- 1,3,5-triazine, - 584.99± 1.50; 2,4,6-tris(2-fluoro-2,2-dinitroethoxy)-l,3,5-triazine, -1109.80±l.53; 2,4-dimethoxy-6-(2-fluoro-2,2-dimtroethoxy)-l,3,5-triazine, -697.08± 1,15; 2-methoxy- 4,6-bis(2-fluoro-2,2-dinitroethoxy)-l,3,5-triazine, -907.71± 2.40; 2-amino-4,6-bis(2-fluoro-2,2-dinitroethoxy)-l,3,5-triazine, - 773-12±1.50.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6664203 | PMC |
| http://dx.doi.org/10.6028/jres.090.018 | DOI Listing |
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