Herein, we describe a soluble iron(II)-phthalocyanine, [Fe(BuPc)(py)] (Pc = phthalocyaninato(2-)), as an effective catalyst in intramolecular C(sp)-H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.
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http://dx.doi.org/10.1039/d1cc04573c | DOI Listing |
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