Calcium nitridonickelate(II) CaNiN has been prepared through a high-temperature and high-pressure azide-mediated redox reaction, demonstrating that this method can stabilise nitrides of late transition metals in relatively high oxidation states. CaNiN crystallizes in the NaHgO structure type and displays low-dimensional antiferromagnetic ordering of Ni spins.
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| http://dx.doi.org/10.1039/d1cc04001d | DOI Listing |
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