A PHP Error was encountered

Severity: Warning

Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests

Filename: helpers/my_audit_helper.php

Line Number: 143

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML

File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

A PHP Error was encountered

Severity: Warning

Message: Attempt to read property "Count" on bool

Filename: helpers/my_audit_helper.php

Line Number: 3100

Backtrace:

File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler

File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global

File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword

File: /var/www/html/index.php
Line: 316
Function: require_once

Molecular Analyses of Petroleum Hydrocarbon Change and Transformation during Petroleum Weathering by Multiple Techniques. | LitMetric

AI Article Synopsis

  • Various analytical methods, including GC-FID, GC-MS, and FT-ICR MS, were employed to study the weathering of four crude oils: Iranian light, Daqing, Shengli, and Tahe crude oils.
  • The findings revealed that the loss of -alkanes during weathering is correlated with their molecular weight, with lower molecular weight compounds being more volatile and experiencing greater loss.
  • Additionally, it was observed that nitrogen compounds like NO and NO2 increased during the weathering process, indicating oxidation alongside hydrocarbon volatilization, which enhances the understanding of petroleum hydrocarbon weathering.

Article Abstract

Various analytical techniques are used to study the weathering process of four crude oils, i.e., Iranian light crude oil, Daqing crude oil, Shengli crude oil, and Tahe crude oil. The molecular composition and structural information of -alkanes, polycyclic aromatic hydrocarbons (PAHs), and heteroatom compounds were characterized by gas chromatography-flame ionization detector (GC-FID), gas chromatography-mass spectrometry (GC-MS), and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), respectively. The results showed that the weathering loss of -alkanes was related to the molecular weight, and the low-molecular-weight (LMW) -alkanes were more volatile. The loss degree of LMW naphthalene and alkylation homologues in PAHs was also higher. With the increase in the alkylation degree, the weathering resistance ability of PAHs was enhanced. In the negative-ion ESI FT-ICR MS mode, a total of 16 classes of compounds were detected for neutral nitrogen compounds and acidic compounds in the four crude oils. With the increase in weathering time, the relative abundances of NO, NO2, and O3S compounds gradually increased. In particular, the NO and NO2 compounds with different condensation degrees increased significantly. These results indicated that in addition to the volatilization of hydrocarbon compounds, nitrogen compounds were also oxidized to a certain extent during the weathering process. The provided information would enrich the understanding of the short-term weathering process of petroleum hydrocarbons.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC8444223PMC
http://dx.doi.org/10.1021/acsomega.1c02846DOI Listing

Publication Analysis

Top Keywords

crude oil
16
weathering process
12
crude oils
8
compounds
8
nitrogen compounds
8
weathering
7
crude
6
molecular analyses
4
analyses petroleum
4
petroleum hydrocarbon
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!

A PHP Error was encountered

Severity: Notice

Message: fwrite(): Write of 34 bytes failed with errno=28 No space left on device

Filename: drivers/Session_files_driver.php

Line Number: 272

Backtrace:

A PHP Error was encountered

Severity: Warning

Message: session_write_close(): Failed to write session data using user defined save handler. (session.save_path: /var/lib/php/sessions)

Filename: Unknown

Line Number: 0

Backtrace: